Fabrication and thermoelectric properties of N-type Bi2Te3 based compounds by spark plasma sintering

被引:2
作者
Lee, DM
Lim, CH
Cho, DC
Shin, SY
Cho, WS
机构
[1] Inha Univ, Coll Engn, Sch Mat Sci & Engn, Inchon 402751, South Korea
[2] Korea Inst Ind Technol, Adv Welding & Joining Technol Team, Inchon 406130, South Korea
来源
ECO-MATERIALS PROCESSING & DESIGN VI | 2005年 / 486-487卷
关键词
Bi2Te3; thermoelectric; Seebeck effect; Peltier effect; spark plasma sintering;
D O I
10.4028/www.scientific.net/MSF.486-487.253
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
N-type Bi2Te3 based thermoelectric compound was prepared by spark plasma sintering with a temperature range of 340 similar to 460 degrees C and powder size of similar to 75 mu m, 76 similar to 150 mu m, 151 similar to 250 mu m. Thermoelectric properties of the compound were measured as a function of the sintering temperature and powder size. With increasing sintering temperature, the electrical resistivity and thermal conductivity of the compound greatly changed because of the increase in relative density. The Seebeck coefficient and electrical resistivity were varied largely with increasing powder size. Therefore, the compound sintered at 460 degrees C, with the powder of similar to 75 mu m, showed a figure of merit of 2.44 x 10(-3)/K. Also, the bending strength was 75MPa.
引用
收藏
页码:253 / 256
页数:4
相关论文
共 10 条
[1]   Effect of oxygen content on thermoelectric properties of sintered Bi-Te based compounds [J].
Cho, DC ;
Lim, CH ;
Lee, DM ;
Shin, SY ;
Lee, CH .
DESIGNING, PROCESSING AND PROPERTIES OF ADVANCED ENGINEERING MATERIALS, PTS 1 AND 2, 2004, 449-4 :905-908
[2]  
MATSUI N, 1997, J JPN SOC POWDER POW, V44, P1121
[3]   Thermoelectric properties of p-type Te doped Bi0.5Sb1.5Te3 fabricated by powder extrusion [J].
Park, K ;
Seo, JH ;
Cho, DC ;
Choi, BH ;
Lee, CH .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2002, 88 (01) :103-106
[4]   EFFECTS OF HEAVY DEFORMATION AND ANNEALING ON ELECTRICAL PROPERTIES OF BI2TE3 [J].
SCHULTZ, JM ;
TILLER, WA ;
MCHUGH, JP .
JOURNAL OF APPLIED PHYSICS, 1962, 33 (08) :2443-&
[5]  
SEO J, 1999, THESIS INHA U KOREA
[6]   Thermoelectric properties of 25%Bi2Te3-75%Sb2Te3 solid solution prepared by hot-pressing method [J].
Shin, HS ;
Ha, HP ;
Hyun, DB ;
Shim, JD ;
Lee, DH .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1997, 58 (04) :671-678
[7]  
Uemura K., 1988, Thermoelectric Semiconductors and their Applications, P145
[8]   Effect of processing parameters on thermoelectric properties of p-type (Bi2Te3)0.25(Sb2Te3)0.75 prepared via BMA-HP method [J].
Yang, J ;
Aizawa, T ;
Yamamoto, A ;
Ohta, T .
MATERIALS CHEMISTRY AND PHYSICS, 2001, 70 (01) :90-94
[9]   Synthesis of filled skutterudite compound La0.75Fe3CoSb12 by spark plasma sintering and effect of porosity on thermoelectric properties [J].
Yang, L ;
Wu, JS ;
Zhang, LT .
JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 364 (1-2) :83-88
[10]   Synthesis and thermoelectric properties of CoSb3 compounds by spark plasma sintering [J].
Zhang, JX ;
Lu, QM ;
Liu, KG ;
Zhang, L ;
Zhou, ML .
MATERIALS LETTERS, 2004, 58 (14) :1981-1984