Copper-Catalyzed C-P Coupling through Decarboxylation

被引：220

作者：

Hu, Jie ^{[1
]}

Zhao, Ning ^{[1
]}

Yang, Bin ^{[1
]}

Wang, Ge ^{[1
]}

Guo, Li-Na ^{[1
]}

Liang, Yong-Min ^{[1
]}

Yang, Shang-Dong ^{[1
]}

机构：

[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 20期

关键词：

catalysis; copper; C-P coupling; decarboxylation; phosphorus; HECK-TYPE OLEFINATION; BIARYL SYNTHESIS; ARYL BROMIDES; POTASSIUM POLYFLUOROBENZOATES; AROMATIC CARBOXYLATES; H-PHOSPHONATES; BOND FORMATION; AMINO-ACIDS; PHOSPHORUS; LIGANDS;

D O I：

10.1002/chem.201003561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An acid for a phosphine: A versatile protocol for preparation of various di(phenyl)phosphoryl oxides was developed by copper-catalyzed decarboxylative coupling of alkenyl, alkynyl carboxylic acids, and N-benzylproline, respectively, with R2P(O)H (see scheme). All classes of products are important precursors for preparation of biologically active molecules and various phosphorus ligands. This finding represents the first example of copper-catalyzed decarboxylative coupling to construct Cï P bonds. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5516 / 5521

页数：6

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