Copper-Catalyzed C-P Coupling through Decarboxylation

被引：224
作者：
Hu, Jie [1 ]
Zhao, Ning [1 ]
Yang, Bin [1 ]
Wang, Ge [1 ]
Guo, Li-Na [1 ]
Liang, Yong-Min [1 ]
Yang, Shang-Dong [1 ]
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 20期
关键词：
catalysis; copper; C-P coupling; decarboxylation; phosphorus; HECK-TYPE OLEFINATION; BIARYL SYNTHESIS; ARYL BROMIDES; POTASSIUM POLYFLUOROBENZOATES; AROMATIC CARBOXYLATES; H-PHOSPHONATES; BOND FORMATION; AMINO-ACIDS; PHOSPHORUS; LIGANDS;
D O I：
10.1002/chem.201003561
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An acid for a phosphine: A versatile protocol for preparation of various di(phenyl)phosphoryl oxides was developed by copper-catalyzed decarboxylative coupling of alkenyl, alkynyl carboxylic acids, and N-benzylproline, respectively, with R2P(O)H (see scheme). All classes of products are important precursors for preparation of biologically active molecules and various phosphorus ligands. This finding represents the first example of copper-catalyzed decarboxylative coupling to construct Cï P bonds. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码：5516 / 5521
页数：6
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