The {001} facets-dependent high photoactivity of BiOCl nanosheets

被引：607
作者：
Ye, Liqun [1 ]
Zan, Ling [1 ]
Tian, Lihong [1 ]
Peng, Tianyou [1 ]
Zhang, Jiujun [2 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] Natl Res Council Canada, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, Canada
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 24期
基金：
中国国家自然科学基金;
关键词：
PHOTOCATALYTIC ACTIVITY; NANOSTRUCTURES; SURFACE;
D O I：
10.1039/c1cc11015b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
BiOCl nanosheets (BiOCl NSs) were synthesized by hydrolyzing a hierarchical flowerlike molecular precursor (Bi-n(Tu)(x)Cl-3n, Tu = thiourea). High photoactivity of {001} facets of BiOCl NSs was observed, and the mechanism was discussed.
引用
收藏
页码：6951 / 6953
页数：3
相关论文
共 25 条
[1]   Bismuth ladder polymers:: structural and thermal studies of [Bi(OCH2CH2)3N]n and [(BixTb1-x(O2C2H2)3N•2H2O]n [J].
Bachman, RE ;
Whitmire, KH ;
Thurston, JH ;
Gulea, A ;
Stavila, O ;
Stavila, V .
INORGANICA CHIMICA ACTA, 2003, 346 :249-255
[2]   Surface studies of nitrogen implanted TiO2 [J].
Batzill, Matthias ;
Morales, Erie H. ;
Diebold, Ulrike .
CHEMICAL PHYSICS, 2007, 339 (1-3) :36-43
[3]   A novel BiOCl film with flowerlike hierarchical structures and its optical properties [J].
Cao, Sihai ;
Guo, Chuanfei ;
Lv, Ying ;
Guo, Yanjun ;
Liu, Qian .
NANOTECHNOLOGY, 2009, 20 (27)
[4]   Strong blue photoluminescence from single-crystalline bismuth oxychloride nanoplates [J].
Deng, Zhengtao ;
Tang, Fangqiong ;
Muscat, Anthony J. .
NANOTECHNOLOGY, 2008, 19 (29)
[5]   Photoactive centers responsible for visible-light photoactivity of N-doped TiO2 [J].
Feng, Caixia ;
Wang, Yan ;
Jin, Zhensheng ;
Zhang, Jiwei ;
Zhang, Shunli ;
Wu, Zhishen ;
Zhang, Zhijun .
NEW JOURNAL OF CHEMISTRY, 2008, 32 (06) :1038-1047
[6]   One-dimensional BiPO4 nanorods and two-dimensional BiOCl lamellae:: Fast low-temperature sonochemical synthesis, characterization, and growth mechanism [J].
Geng, J ;
Hou, WH ;
Lv, YN ;
Zhu, JJ ;
Chen, HY .
INORGANIC CHEMISTRY, 2005, 44 (23) :8503-8509
[7]   Surface phases and photocatalytic activity correlation of Bi2O3/Bi2O4-x nanocomposite [J].
Hameed, Abdul ;
Montini, Tiziano ;
Gombac, Valentina ;
Fornasiero, Paolo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (30) :9658-+
[8]   Synthesis of Tin Dioxide Octahedral Nanoparticles with Exposed High-Energy {221} Facets and Enhanced Gas-Sensing Properties [J].
Han, Xiguang ;
Jin, Mingshang ;
Xie, Shuifen ;
Kuang, Qin ;
Jiang, Zhiyuan ;
Jiang, Yaqi ;
Xie, Zhaoxiong ;
Zheng, Lansun .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (48) :9180-9183
[9]   Syntheses and Properties of Micro/Nanostructured Crystallites with High-Energy Surfaces [J].
Jiang, Zhi-Yuan ;
Kuang, Qin ;
Xie, Zhao-Xiong ;
Zheng, Lan-Sun .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (21) :3634-3645
[10]   Synthesis, characterization and assembly of BiOCl nanostructure and their photocatalytic properties [J].
Lei, Yongqian ;
Wang, Guanhua ;
Song, Shuyan ;
Fan, Weiqiang ;
Zhang, Hongjie .
CRYSTENGCOMM, 2009, 11 (09) :1857-1862
123