Aluminothermic reduction enabled synthesis of silicon hollow microspheres from commercialized silica nanoparticles for superior lithium storage

被引:52
作者
Zhou, Zheng-Wei [1 ]
Liu, Yi-Tao [1 ,2 ]
Xie, Xu-Ming [1 ]
Ye, Xiong-Ying [2 ]
机构
[1] Tsinghua Univ, Dept Chem Engn, Key Lab Adv Mat MOE, Beijing 100084, Peoples R China
[2] Tsinghua Univ, State Key Lab Precis Measurement Technol & Instru, Dept Precis Instrument, Beijing 100084, Peoples R China
基金
中国博士后科学基金;
关键词
ION BATTERY ANODES; ENERGY-STORAGE; SI NANOPARTICLES; NANOSPHERES; NANOWIRES; FABRICATION; COMPOSITE; CAPACITY; NETWORK; SPHERES;
D O I
10.1039/c6cc03766f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the aluminothermic reduction enabled synthesis of silicon hollow microspheres from commercialized silica nanoparticles by controlled transformation and organization. The synergistically integrated merits of a simple process and delicate structural design lay a basis for developing an industrially viable silicon anode with optimized electrochemical performances.
引用
收藏
页码:8401 / 8404
页数:4
相关论文
共 38 条
  • [1] High performance silicon-based anodes in solid-state lithium batteries
    Cervera, Rinlee B.
    Suzuki, Naoki
    Ohnishi, Tsuyoshi
    Osada, Minoru
    Mitsuishi, Kazutaka
    Kambara, Takayoshi
    Takada, Kazunori
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (02) : 662 - 666
  • [2] High-performance lithium battery anodes using silicon nanowires
    Chan, Candace K.
    Peng, Hailin
    Liu, Gao
    McIlwrath, Kevin
    Zhang, Xiao Feng
    Huggins, Robert A.
    Cui, Yi
    [J]. NATURE NANOTECHNOLOGY, 2008, 3 (01) : 31 - 35
  • [3] Facile fabrication of Si mesoporous nanowires for high-capacity and long-life lithium storage
    Chen, Jizhang
    Yang, Li
    Rousidan, Saibihai
    Fang, Shaohua
    Zhang, Zhengxi
    Hirano, Shin-ichi
    [J]. NANOSCALE, 2013, 5 (21) : 10623 - 10628
  • [4] One-step synthesis of superparamagnetic monodisperse porous Fe3O4 hollow and core-shell spheres
    Cheng, Wei
    Tang, Kaibin
    Qi, Yunxia
    Sheng, Jie
    Liu, Zhongpin
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (09) : 1799 - 1805
  • [5] Surface Binding of Polypyrrole on Porous Silicon Hollow Nanospheres for Li-Ion Battery Anodes with High Structure Stability
    Du, Fei-Hu
    Li, Bo
    Fu, Wei
    Xiong, Yi-Jun
    Wang, Kai-Xue
    Chen, Jie-Sheng
    [J]. ADVANCED MATERIALS, 2014, 26 (35) : 6145 - 6150
  • [6] Nanosilicon-Coated Graphene Granules as Anodes for Li-Ion Batteries
    Evanoff, Kara
    Magasinski, Alexandre
    Yang, Junbing
    Yushin, Gleb
    [J]. ADVANCED ENERGY MATERIALS, 2011, 1 (04) : 495 - 498
  • [7] Lithium Intercalation Behavior in Multilayer Silicon Electrodes
    Fister, Tim T.
    Esbenshade, Jennifer
    Chen, Xiao
    Long, Brandon R.
    Shi, Bing
    Schlepuetz, Christian M.
    Gewirth, Andrew A.
    Bedzyk, Michael J.
    Fenter, Paul
    [J]. ADVANCED ENERGY MATERIALS, 2014, 4 (07)
  • [8] Si nanoparticles-nested inverse opal carbon supports for highly stable lithium-ion battery anodes
    Gueon, Donghee
    Kang, Da-Young
    Kim, Jung Sub
    Kim, Tae Yong
    Lee, Joong Kee
    Moon, Jun Hyuk
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (47) : 23684 - 23689
  • [9] A Critical Size of Silicon Nano-Anodes for Lithium Rechargeable Batteries
    Kim, Hyejung
    Seo, Minho
    Park, Mi-Hee
    Cho, Jaephil
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (12) : 2146 - 2149
  • [10] Scalable synthesis of silicon nanosheets from sand as an anode for Li-ion batteries
    Kim, Won-Sik
    Hwa, Yoon
    Shin, Jung-Hoo
    Yang, Myung
    Sohn, Hun-Joon
    Hong, Seong-Hyeon
    [J]. NANOSCALE, 2014, 6 (08) : 4297 - 4302