Vapour-liquid equilibrium for the 2-methylpropane plus methanol, +ethanol, +2-propanol, +2-butanol and +2-methyl-2-propanol systems at 313.15 K

被引：13

作者：

Ouni, T ^{[1
]}

Zaytseva, A ^{[1
]}

Uusi-Kyyny, P ^{[1
]}

Pokki, JP ^{[1
]}

Aittamaa, J ^{[1
]}

机构：

[1] Aalto Univ, Dept Chem Technol, FIN-02015 Helsinki, Finland

来源：

FLUID PHASE EQUILIBRIA | 2005年 / 232卷 / 1-2期

关键词：

vapour-liquid equilibrium; predictive methods; COSMO-RS; 2-methylpropane; alcohol;

D O I：

10.1016/j.fluid.2005.03.016

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

An automated total pressure measurement apparatus was used to measure PTz data that was regressed into PTxy data using the method of Barker (1953). The isothermal vapour-liquid equilibrium measurements were carried out for the five binary systems 2-methylpropane + methanol, +ethanol, +2-propanol, +2-butanol and +2-methyl-2-propanol at 313.15 K. Error analysis of the measured results is presented. Measurements were compared with predictions given by UNIFAC and COSMO-RS. All systems exhibited positive deviation from Raoult's law and azeotropic behaviour was found for the systems 2-methylpropane + methanol and 2-methylpropane + ethanol. (c) 2005 Elsevier B.V All rights reserved.

引用

页码：90 / 99

页数：10

共 31 条

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