Metal-Catalyzed Synthesis of Alternating Copolymers

被引：106

作者：

Brule, Emilie ^{[1
,2
]}

Guo, Jia ^{[1
]}

Coates, Geoffrey W. ^{[3
]}

Thomas, Christophe M. ^{[1
]}

机构：

[1] Chim ParisTech, CNRS, UMR 7223, F-75231 Paris, France

[2] Univ Paris 06, F-75005 Paris, France

[3] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2011年 / 32卷 / 02期

关键词：

alternation; catalysis; copolymers; sequence; synthesis; RING-OPENING COPOLYMERIZATION; ETHYLENE-NORBORNENE COPOLYMERS; SUPERCRITICAL CARBON-DIOXIDE; DIIMINATE ZINC CATALYSTS; N-SUBSTITUTED MALEIMIDES; PROPYLENE-OXIDE; MECHANISTIC ASPECTS; CYCLOHEXENE OXIDE; PALLADIUM(II) COMPLEXES; ALUMINUM PORPHYRIN;

D O I：

10.1002/marc.201000524

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The creation of polymers with a high degree of sequence and/or stereocontrol represents an exciting frontier in materials science. In order to obtain alternating polymers, coordination polymerization using well-defined metal complexes has played a leading role in the last two decades. In the following paper, we will describe, selected published efforts to achieve these research goals using discrete structurally well-characterized metal complexes.

引用

页码：169 / 185

页数：17

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