Synthesis and high-temperature thermoelectric properties of Ni3GaSb and Ni3InSb

被引:6
作者
Suriwong, Tawat [2 ]
Kurosaki, Ken [1 ]
Thongtem, Somchai [2 ]
Harnwunggmoung, Adul [1 ]
Sugahara, Tohru [1 ]
Plirdpring, Theerayuth [1 ]
Ohishi, Yuji [1 ]
Muta, Hiroaki [1 ]
Yamanaka, Shinsuke [1 ,3 ]
机构
[1] Osaka Univ, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Chiang Mai Univ, Dept Phys & Mat Sci, Fac Sci, Chiang Mai 50200, Thailand
[3] Univ Fukui, Res Inst Nucl Engn, Fukui 9108507, Japan
关键词
Ni3GaSb; Ni3InSb; Thermoelectric; Seebeck coefficient; Electrical resistivity; Thermal conductivity; EFFICIENCY; GALLIUM; GROWTH; INDIUM; INSB;
D O I
10.1016/j.jallcom.2011.01.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ni3GaSb and Ni3InSb were successfully synthesized by the direct reaction of Ni and GaSb or InSb. The XRD patterns and the lattice parameters of these compounds were in good agreement with the literature data. The Seebeck coefficient (S), the electrical resistivity (rho), and the thermal conductivity (kappa) of Ni3GaSb and Ni3InSb were examined in the temperature range from room temperature to 1073 K. Both compounds indicated metal-like characteristics. The power factor (S-2 rho(-1)) values increased with temperature and reached maximum at 1073 K. The kappa and the dimensionless figure of merit ZT of both samples increased with temperature. The maximum values of the ZT of Ni3GaSb and Ni3InSb were obtained at 1073K to be 0.022 and 0.023, respectively. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:4014 / 4017
页数:4
相关论文
共 18 条
  • [1] VERY HIGH QUANTUM EFFICIENCY GASB MESA PHOTODETECTORS BETWEEN 1.3 AND 1.6-MU-M
    CAPASSO, F
    PANISH, MB
    SUMSKI, S
    FOY, PW
    [J]. APPLIED PHYSICS LETTERS, 1980, 36 (02) : 165 - 167
  • [2] On the conduction mechanism of p-type GaSb bulk crystal
    Ebnalwaled, A. A.
    [J]. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2010, 174 (1-3): : 285 - 289
  • [3] Evolution of growth and enhancement in power factor of InSb bulk crystal
    Ebnalwaled, A. A.
    [J]. JOURNAL OF CRYSTAL GROWTH, 2009, 311 (19) : 4385 - 4390
  • [4] GROWTH, MORPHOLOGY AND ELECTRICAL-TRANSPORT PROPERTIES OF MOCVD-GROWN P-INSB
    EGAN, RJ
    CHIN, VWL
    TANSLEY, TL
    [J]. SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1994, 9 (09) : 1591 - 1597
  • [5] Enhancement of thermoelectric efficiency in PbTe by distortion of the electronic density of states
    Heremans, Joseph P.
    Jovovic, Vladimir
    Toberer, Eric S.
    Saramat, Ali
    Kurosaki, Ken
    Charoenphakdee, Anek
    Yamanaka, Shinsuke
    Snyder, G. Jeffrey
    [J]. SCIENCE, 2008, 321 (5888) : 554 - 557
  • [6] Three-dimensional visualization in powder diffraction
    Izumi, Fujio
    Momma, Koichi
    [J]. APPLIED CRYSTALLOGRAPHY XX, 2007, 130 : 15 - 20
  • [7] THE EXISTENCE OF NI3MSB PHASES IN TERNARY NICKEL-M-ANTIMONY SYSTEMS (WHERE M REPRESENTS ALUMINUM, GALLIUM, OR INDIUM)
    JAN, CH
    CHANG, YA
    [J]. JOURNAL OF MATERIALS RESEARCH, 1991, 6 (12) : 2660 - 2665
  • [8] JCPDS-ICDD, 2001, POWD DIFFR FIL
  • [9] New bulk Materials for Thermoelectric Power Generation: Clathrates and Complex Antimonides
    Kleinke, Holger
    [J]. CHEMISTRY OF MATERIALS, 2010, 22 (03) : 604 - 611
  • [10] Ag9TITe5:: A high-performance thermoelectric bulk material with extremely low thermal conductivity -: art. no. 061919
    Kurosaki, K
    Kosuga, A
    Muta, H
    Uno, M
    Yamanaka, S
    [J]. APPLIED PHYSICS LETTERS, 2005, 87 (06)