Practical methods for synthesizing four incompletely condensed silsesquioxanes from a single R8Si8O12 framework

被引:45
作者
Feher, FJ [1 ]
Soulivong, D [1 ]
Nguyen, F [1 ]
机构
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 96297 USA
关键词
D O I
10.1039/a802670j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of (c-C6H11)(8)Si8O12 1 with triflic acid (TfOH) can produce two different ditriflates with the formula (c-C6H11)(8)Si8O11(OTf)(2), which can be hydrolyzed selectively to four different incompletely condensed silsesquioxane frameworks with the formula (c-C6H11)(8)Si8O11(OH)(2) (2, 4, 7 and 8).
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页码:1279 / 1280
页数:2
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