Starch saccharification by carbon-based solid acid catalyst

被引：36
作者：
Yamaguchi, Daizo [2 ]
Hara, Michikazu [1 ,2 ]
机构：
[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Kanagawa Acad Sci & Technol, Takatsu Ku, Kawasaki, Kanagawa 2130012, Japan
来源：
SOLID STATE SCIENCES | 2010年 / 12卷 / 06期
基金：
日本学术振兴会;
关键词：
Solid acid catalyst; Hydrolysis; Cornstarch; alpha-1,4 Glucan; Glucose; RESPONSE-SURFACE METHODOLOGY; ARTIFICIAL NEURAL-NETWORK; AMORPHOUS-CARBON; BEARING SO3H; OH GROUPS; HYDROLYSIS; CHEMICALS; BIOMASS; UNIT; COOH;
D O I：
10.1016/j.solidstatesciences.2009.12.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrolysis of cornstarch using a highly active solid acid catalyst, a carbon material bearing SO3H, COOH and OH groups, was investigated at 353-393 K through an analysis of variance (ANOVA) and an artificial neural network (ANN). ANOVA revealed that reaction temperature and time are significant parameters for the catalytic hydrolysis of starch. The ANN model indicated that the reaction efficiency reaches a maximum at an optimal condition (water, 0.8-1.0 mL; starch, 0.3-0.4 g; catalyst, 0.3 g; reaction temperature, 373 K; reaction time, 3 h). The relationship between the reaction and these parameters is discussed on the basis of the reaction mechanism. (C) 2009 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：1018 / 1023
页数：6
相关论文
共 25 条
  • [1] Box GEP., 1960, Technometrics, V2, P455, DOI [10.1080/00401706.1960.10489912, DOI 10.1080/00401706.1960.10489912, 10.2307/1266454]
  • [2] Chemical routes for the transformation of biomass into chemicals
    Corma, Avelino
    Iborra, Sara
    Velty, Alexandra
    [J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2411 - 2502
  • [3] Powder diffraction indexing as a pattern recognition problem: A new approach for unit cell determination based on an artificial neural network
    Habershon, S
    Cheung, EY
    Harris, KDM
    Johnston, RL
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (05) : 711 - 716
  • [4] Bio-ethanol -: the fuel of tomorrow from the residues of today
    Hahn-Hagerdal, B.
    Galbe, M.
    Gorwa-Grauslund, M. F.
    Liden, G.
    Zacchi, G.
    [J]. TRENDS IN BIOTECHNOLOGY, 2006, 24 (12) : 549 - 556
  • [5] A REVIEW OF RESPONSE SURFACE METHODOLOGY - A LITERATURE SURVEY
    HILL, WJ
    HUNTER, WG
    [J]. TECHNOMETRICS, 1966, 8 (04) : 571 - &
  • [6] Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering
    Huber, George W.
    Iborra, Sara
    Corma, Avelino
    [J]. CHEMICAL REVIEWS, 2006, 106 (09) : 4044 - 4098
  • [7] Adsorption-Enhanced Hydrolysis of β-1,4-Glucan on Graphene-Based Amorphous Carbon Bearing SO3H, COOH, and OH Groups
    Kitano, Masaaki
    Yamaguchi, Daizo
    Suganuma, Satoshi
    Nakajima, Kiyotaka
    Kato, Hideki
    Hayashi, Shigenobu
    Hara, Michikazu
    [J]. LANGMUIR, 2009, 25 (09) : 5068 - 5075
  • [8] Application of neural network to estimation of catalyst deactivation in methanol conversion
    Kito, S
    Satsuma, A
    Ishikura, T
    Niwa, M
    Murakami, Y
    Hattori, I
    [J]. CATALYSIS TODAY, 2004, 97 (01) : 41 - 47
  • [9] Recent progress in synthesis of fine and specialty chemicals from wood and other biomass by heterogeneous catalytic processes
    Maeki-Arvela, Päivi
    Holmbom, Bjarne
    Salmi, Tapio
    Murzin, Dmitry Yu.
    [J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2007, 49 (03): : 197 - 340
  • [10] RESPONSE-SURFACE METHODOLOGY - 1966-1988
    MYERS, RH
    KHURI, AI
    CARTER, WH
    [J]. TECHNOMETRICS, 1989, 31 (02) : 137 - 157
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