Flash co-pyrolysis of biomass with polyhydroxybutyrate: Part 1. Influence on bio-oil yield, water content, heating value and the production of chemicals

被引：49

作者：

Cornelissen, T. ^{[1
]}

Jans, M. ^{[2
]}

Yperman, J. ^{[1
]}

Reggers, G. ^{[1
]}

Schreurs, S. ^{[2
]}

Carleer, R. ^{[1
]}

机构：

[1] Hasselt Univ, Lab Appl Chem, CMK, B-3590 Diepenbeek, Belgium

[2] XIOS, NuTeC, Dept IWT, B-3590 Diepenbeek, Belgium

来源：

FUEL | 2008年 / 87卷 / 12期

关键词：

flash co-pyrolysis; willow; polyhydroxybutyrate; pyrolytic water; bio-oil;

D O I：

10.1016/j.fuel.2008.02.024

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Bio-oil obtained via flash pyrolysis shows potential to be applied as a renewable fuel. However, bio-oil often contains high amounts of water, which is a major drawback for its application. The influence of a biopolymer - polyhydroxybutyrate (PHB) on the pyrolysis of willow is investigated using a semi-continuous home-built pyrolysis reactor. The flash co-pyrolysis of willow/PHB blends (w/w ratio 7:1, 3:1, 2:1 and 1:1) clearly shows particular merits: a synergetic increase in pyrolysis yield, a synergetic reduction of the water content in bio-oil, an increase in heating value, and a production of easily separable chemicals. The occurrence of synergetic interactions is observed based on a comparison between the actual pyrolysis results of the willow/PHB blends, the theoretical pyrolysis results calculated from the reference pyrolysis experiments (pure willow and pure PHB) and their respective w/w ratio. The co-pyrolysis of 1:1 willow/PHB shows the best overall results. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：2523 / 2532

页数：10

共 24 条

[1] Thermal degradation of poly[(R)-3-hydroxybutyrate], poly[ε-caprolactone], and poly[(S)-lactide] [J].

Aoyagi, Y ;

Yamashita, K ;

Doi, Y .

POLYMER DEGRADATION AND STABILITY, 2002, 76 (01) :53-59

[2] Modeling, simulation and estimation of optimum parameters in pyrolysis of biomass [J].

Babu, BV ;

Chaurasia, AS .

ENERGY CONVERSION AND MANAGEMENT, 2003, 44 (13) :2135-2158

[3] An overview of fast pyrolysis of biomass [J].

Bridgwater, AV ;

Meier, D ;

Radlein, D .

ORGANIC GEOCHEMISTRY, 1999, 30 (12) :1479-1493

[4] Flash co-pyrolysis of biomass with polylactic acid. Part 1: Influence on bio-oil yield and heating value [J].

Cornelissen, T. ;

Yperman, J. ;

Reggers, G. ;

Schreurs, S. ;

Carleer, R. .

FUEL, 2008, 87 (07) :1031-1041

[5] Overview of applications of biomass fast pyrolysis oil [J].

Czernik, S ;

Bridgwater, AV .

ENERGY & FUELS, 2004, 18 (02) :590-598

[6] An overview of Biomass pyrolysis [J].

Demirbas, A ;

Arin, G .

ENERGY SOURCES, 2002, 24 (05) :471-482

[7]

European Science Foundation, 2000, ESF Science Policy Briefing, P1

[8] Application of pyrolysis/gas chromatography/Fourier transform infrared spectroscopy and TGA techniques in the study of thermal degradation of poly (3-hydroxybutyrate) [J].

Gonzalez, A ;

Irusta, L ;

Fernández-Berridi, MJ ;

Iriarte, M ;

Iruin, JJ .

POLYMER DEGRADATION AND STABILITY, 2005, 87 (02) :347-354

[9] Effect of lignin particles as a nucleating agent on crystallization of poly(3-hydroxybutyrate) [J].

Kai, WH ;

He, Y ;

Asakawa, N ;

Inoue, Y .

JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 94 (06) :2466-2474

[10]

KALNINS M, 1999, REC REC REINT 1999 C

← 1 2 3 →