A new H2O2/Acid anhydride system for the iodoarene-catalyzed C-C bond-forming reactions of phenols

被引：139

作者：

Dohi, Toshifumi ^{[1
]}

Minamitsuji, Yutaka ^{[1
]}

Maruyama, Akinobu ^{[1
]}

Hirose, Satoshi ^{[1
]}

Kita, Yasuyuki ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 16期

关键词：

D O I：

10.1021/ol801321f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have succeeded in the first versatile iodoarene-catalyzed C-C bond-forming reactions by development of a new reoxidation system at low temperatures using stoichiometric bis(trifluoroacetyl) peroxide A in 2,2,2-trifluoroethanol (TFE). The catalytic system supplies a wide range of substrates and functional availabilities sufficient to be used in the key synthetic process of producing biologically important Amaryllidaceae alkaloids.

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页码：3559 / 3562

页数：4

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