Synthesis and characterization of manganese(III) complexes of Schiff bases derived from amino acids and 2-hydroxy-1-naphthaldehyde

被引：34

作者：

Sakiyan, I ^{[1
]}

Gündüz, N ^{[1
]}

Gündüz, T ^{[1
]}

机构：

[1] Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2001年 / 31卷 / 07期

关键词：

D O I：

10.1081/SIM-100106856

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New complexes of Mn(III) with Schiff bases obtained by the condensation of 2-hydroxy-1-naphthaldehyde with glycine, L-alanine, L-phenylalanine, L-histidine, L-tryptophan and L-threonine have been synthesized and characterized by elemental analyses, UV, IR, magnetic susceptibility, thermogravimetry and non-aqueous titration. These complexes are coordinated through the ONO donor set derived from the carboxyl, imino and phenoxy groups of the ligands. Furthermore, the Schiff bases were obtained as solids and their structures were determined by IR, UV, H-1 NMR to compare with those of the complexes.

引用

页码：1175 / 1187

页数：13

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