Optimizing hole-injection in organic electroluminescent devices by modifying CuPc/NPB interface

被引:12
作者
Jiang, Meng-Dan [2 ]
Lee, Pei-Yu [1 ]
Chiu, Tien-Lung [1 ]
Lin, Hong-Cheu [2 ]
Lee, Jiun-Haw [3 ,4 ]
机构
[1] Yuan Ze Univ, Dept Photon Engn, Tao Yuan, Taiwan
[2] Natl Chiao Tung Univ, Dept Mat Sci & Engn, Hsinchu, Taiwan
[3] Natl Taiwan Univ, Grad Inst Photon & Optoelect, Taipei 10764, Taiwan
[4] Natl Taiwan Univ, Dept Elect, Taipei 10764, Taiwan
关键词
Organic light-emitting device; Remote pulsed Ar plasma; Hole-blocking; Layer; LIGHT-EMITTING DEVICES; BUFFER LAYER; DEGRADATION MECHANISM; COPPER PHTHALOCYANINE; PERFORMANCE; CATHODE; CSF;
D O I
10.1016/j.synthmet.2011.06.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This investigation discusses the performance of an organic light-emitting device (OLED) with ultraviolet (UV) illuminated and remote pulsed Ar plasma (RPAP), treated copper phthalcyanine (CuPc) thin film on an indium tin oxide anode as the hole-blocking layer. UV treatment increased the driving voltage, the current efficiency decreased at the same time due to the poor sticking probability of NPB on the CuPc surface. By contrast, the driving voltage reduction and current efficiency enhancement were achieved at the same time for the OLED with the RPAP treated CuPc. Besides this, in such device, the thickness of CuPc affects seldom the current density-voltage-luminance characteristics. The surface characteristics of these processed CuPc thin films were investigated by using atomic force microscope, contact angle and X-ray photoelectron spectroscopy measurements, which showed the CuPc/, N,N'-bis-(1-naphthyl)-N,N'-dipheny1-1,1'-bipheny1-4,4'-diamine (NPB) interface was crucial to not only the interface energy barrier, but also the following NPB growth, mode. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1828 / 1831
页数:4
相关论文
共 28 条
[1]   Effect of plasma treatment on the electrical and electroluminescent properties of poly(p-phenylene vinylene) light emitting diodes [J].
Atreya, M ;
Li, S ;
Kang, ET ;
Neoh, KG ;
Tan, KL .
POLYMER DEGRADATION AND STABILITY, 1999, 63 (01) :53-59
[2]   Degradation mechanism of small molecule-based organic light-emitting devices [J].
Aziz, H ;
Popovic, ZD ;
Hu, NX ;
Hor, AM ;
Xu, G .
SCIENCE, 1999, 283 (5409) :1900-1902
[3]   Investigation of internal processes in organic light-emitting devices using thin sensing layers [J].
Beierlein, TA ;
Ruhstaller, B ;
Gundlach, DJ ;
Riel, H ;
Karg, S ;
Rost, C ;
Riess, W .
SYNTHETIC METALS, 2003, 138 (1-2) :213-221
[4]   Impact of the metal cathode and CsF buffer layer on the performance of organic light-emitting devices [J].
Chan, MY ;
Lai, SL ;
Fung, MK ;
Lee, CS ;
Lee, ST .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (10) :5397-5402
[5]   Oxadiazole host for a phosphorescent organic light-emitting device [J].
Chiu, Tien-Lung ;
Lee, Pei-Yu ;
Lee, Jiun-Haw ;
Hsiao, Chih-Hung ;
Leung, Man-Kit ;
Lee, Chung-Chieh ;
Chen, Chen-Yu ;
Yang, Chih-Chiang .
JOURNAL OF APPLIED PHYSICS, 2011, 109 (08)
[6]   Optical and electrical characteristics of Ag-doped perylene diimide derivative [J].
Chiu, Tien-Lung ;
Xu, Wei-Feng ;
Lin, Chi-Feng ;
Lee, Jiun-Haw ;
Chao, Chun-Chieh ;
Leung, Man-Kit .
APPLIED PHYSICS LETTERS, 2009, 94 (01)
[7]   Hole injection or blocking?: The role of CuPc in Alq3-based organic light-emitting devices [J].
Divayana, Y ;
Chen, BJ ;
Sun, XW ;
Wong, TKS ;
Sarma, KR ;
Hu, X .
JOURNAL OF CRYSTAL GROWTH, 2006, 288 (01) :105-109
[8]   Combined photoemission/in vacuo transport study of the indium tin oxide/copper phthalocyanine/N,N′-diphenyl-N,N′-bis(l-naphthyl)-1,1′biphenyl-4,4"diamine molecular organic semiconductor system [J].
Hill, IG ;
Kahn, A .
JOURNAL OF APPLIED PHYSICS, 1999, 86 (04) :2116-2122
[9]   Controlling hole injection in organic electroluminescent device by sputter-grown Cu-phthalocyanine thin films [J].
Kim, SC ;
Lee, GB ;
Choi, MW ;
Roh, Y ;
Whang, CN ;
Jeong, K ;
Lee, JG ;
Kim, S .
APPLIED PHYSICS LETTERS, 2001, 78 (10) :1445-1447
[10]   Interfacial electronic structures in an organic light-emitting diode [J].
Lee, ST ;
Wang, YM ;
Hou, XY ;
Tang, CW .
APPLIED PHYSICS LETTERS, 1999, 74 (05) :670-672