Experimental and kinetic modeling study of combustion of JP-8, its surrogates and components in laminar premixed flows

Experimental and kinetic modeling studies are carried out to characterize premixed combustion of jet fuels, their surrogates, and reference components in laminar nonuniform flows. In previous studies, it was established that the Aachen surrogate made up of 80% n-decane and 20% trimethylbenzene by weight, and surrogate C made up of 57% n-dodecane, 21% methylcyclohexane and 22% o-xylene by weight, reproduce key aspects of combustion of jet fuels in laminar nonpremixed flows. Here, these surrogates and a jet fuel are tested in premixed, nonuniform flows. The counterflow configuration is employed, and critical conditions of extinction are measured. In addition, the reference components tested are n-heptane, n-decane, n-dodecane, methylcyclohexane, trimethylbenzene, and o-xylene. Measured critical conditions of extinction of the Aachen surrogate and surrogate C are compared with those for the jet fuel. In general the alkanes n-heptane, n-decane, and n-dodecane, and methylcyclohexane are found to be more reactive than the aromatics o-xylene and trimethylbenzene. Flame structure and critical conditions of extinction are predicted for the reference components and the surrogates using a semi-detailed kinetic model. The predicted values are compared with experimental data. Sensitivity analysis shows that the lower reactivity of the aromatic species arises from the formation of resonantly stabilized radicals. These radicals are found to have a scavenging effect. The present study on premixed flows together with previous studies on nonpremixed flows show that the Aachen surrogate and surrogate C reproduce many aspects of premixed and nonpremixed combustion of jet fuels.