Bis(μ-2-phenylquinoline-4-carboxylato)bis[aqua(1,10-phenanthroline)(2-phenylquinoline-4-carboxylato)manganese(II)] dihydrate

被引:5
作者
Li, Wei-Wei [1 ]
Bing, Yue [1 ]
Zha, Mei-Qin [1 ]
Li, Tian-Hua [1 ]
Li, Xing [1 ]
机构
[1] Ningbo Univ, Fac Mat Sci & Chem Engn, Ningbo 315211, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
DNA-BINDING; COMPLEXES;
D O I
10.1107/S1600536811039341
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the centrosymmetric dinuclear title complex, [Mn-2(C16H10NO2)(4)(C12H8N2)(2)(H2O)(2)]center dot 2H(2)O, the Mn-II cation is in a distorted octahedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenylquinoline-4-carboxylate anions. A pair of 2-phenylquinoline-4-carboxylate anions bridge two Mn cations, forming the dinuclear molecule. An intramoleculr O-H center dot center dot center dot O hydrogen bond occurs. Intermolecular O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds are present in the crystal structure.
引用
收藏
页码:M1464 / U1491
页数:14
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