Role of Crystalline Structure in Allyl Alcohol Selective Oxidation over Mo3VOx Complex Metal Oxide Catalysts

被引：13

作者：

Murayama, Toru ^{[1
,2
]}

Katryniok, Benjamin ^{[3
,4
]}

Heyte, Svetlana ^{[3
]}

Araque, Marcia ^{[3
,4
]}

Ishikawa, Satoshi ^{[1
,6
]}

Dumeignil, Franck ^{[3
,5
]}

Paul, Sebastien ^{[3
,4
]}

Ueda, Wataru ^{[1
,6
]}

机构：

[1] Hokkaido Univ, Inst Catalysis, N-21 W-10, Sapporo, Hokkaido 0010021, Japan

[2] Tokyo Metropolitan Univ, Res Ctr Gold Chem, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan

[3] CNRS, UMR 8181, UCCS, Cite Sci, Villeneuve Dascq, France

[4] Ecole Cent Lille, Villeneuve Dascq, France

[5] Univ Lille, Villeneuve Dascq, France

[6] Kanagawa Univ, Kanagawa Ku, Yokohama, Kanagawa, Japan

来源：

CHEMCATCHEM | 2016年 / 8卷 / 14期

关键词：

allylic compounds; hydrothermal synthesis; molybdenum; oxidation; vanadium; ACRYLIC-ACID; ORTHORHOMBIC MO3VOX; GLYCEROL; DEHYDRATION; ACROLEIN; ETHANE; OXIDEHYDRATION; TRANSFORMATION; PHASE; FIELD;

D O I：

10.1002/cctc.201600430

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The role of the crystalline phase of Mo3VOx in the catalytic oxidation of allyl alcohol over four kinds of crystalline (orthorhombic, trigonal, tetragonal, amorphous) Mo3VOx catalysts was investigated to determine the active sites for the reactions. Tetragonal Mo3VOx was found less active for the formation of acrylic acid from allyl alcohol, although acrolein was obtained selectively at higher temperature. For orthorhombic and trigonal Mo3VOx catalyst, allyl alcohol converted to acrolein and propanal competitively at the mouth of the heptagonal channel over the a-b plane of the rod-type crystalline particles, and these aldehydes were oxidized consecutively to acrylic acid. Acrylic acid was formed effectively at increased reaction temperature over orthorhombic, trigonal and amorphous Mo3VOx catalysts, and the maximum yields of acrylic acid were 73% for the orthorhombic Mo3VOx catalyst and 72% for the trigonal Mo3VOx catalyst at 350 degrees C.

引用

页码：2415 / 2420

页数：6

共 25 条

[11] Recent Developments in the Field of Catalytic Dehydration of Glycerol to Acrolein [J].

Katryniok, Benjamin ;

Paul, Sebastien ;

Dumeignil, Franck .

ACS CATALYSIS, 2013, 3 (08) :1819-1834

[12] Conversion of glycerol into allyl alcohol over potassium-supported zirconia-iron oxide catalyst [J].

Konaka, Aya ;

Tago, Teruoki ;

Yoshikawa, Takuya ;

Nakamura, Ayaka ;

Masuda, Takao .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 146 :267-273

[13] An orthorhombic Mo3VOx catalyst most active for oxidative dehydrogenation of ethane among related complex metal oxides [J].

Konya, Takeshi ;

Katou, Tomokazu ;

Murayama, Toru ;

Ishikawa, Satoshi ;

Sadakane, Masahiro ;

Buttrey, Douglas ;

Ueda, Wataru .

CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (02) :380-387

[14]

Krahling L., 2012, ULLMANNS ENCY IND CH

[15]

Murib J. H., 1977, US Pat., Patent No. 4051181

[16] Direct oxidative transformation of glycerol to acrylic acid over Nb-based complex metal oxide catalysts [J].

Omata, Kaori ;

Matsumoto, Keeko ;

Murayama, Toru ;

Ueda, Wataru .

CATALYSIS TODAY, 2016, 259 :205-212

[17] Direct Oxidative Transformation of Glycerol into Acrylic Acid over Phosphoric Acid-added W-V-Nb Complex Metal Oxide Catalysts [J].

Omata, Kaori ;

Matsumoto, Keeko ;

Murayama, Toru ;

Ueda, Wataru .

CHEMISTRY LETTERS, 2014, 43 (04) :435-437

[18] Hydrothermal synthesis of W-Nb complex metal oxides and their application to catalytic dehydration of glycerol to acrolein [J].

Omata, Kaori ;

Izumi, Shoko ;

Murayama, Toru ;

Ueda, Wataru .

CATALYSIS TODAY, 2013, 201 :7-11

[19] Crystalline Mo-V-W-mixed Oxide with Orthorhombic and Trigonal Structures as Highly Efficient Oxidation Catalysts of Acrolein to Acrylic Acid [J].

Qiu, Chuntian ;

Chen, Chen ;

Ishikawa, Satoshi ;

Murayama, Toru ;

Ueda, Wataru .

TOPICS IN CATALYSIS, 2014, 57 (14-16) :1163-1170

[20] Selective dehydration of diols to allylic alcohols catalyzed by ceria [J].

Sato, S ;

Takahashi, R ;

Sodesawa, T ;

Honda, N ;

Shimizu, H .

CATALYSIS COMMUNICATIONS, 2003, 4 (02) :77-81

← 1 2 3 →