Compaction pressure effect on microstructure and electrochemical performance of GdBaCo2O5+δ cathode for IT-SOFCs

In order to optimize the morphology of starting powder, raw GBCO powder synthesized via solid state reaction was repeatedly compacted by uniaxial die pressing at two apparent compaction pressures of 500 and 1000 MPa. The particle size distribution curves and SEM images indicated that, with increasing compaction pressure and number of compaction times, the larger particles in the powder were gradually broken apart and the particle size became small and uniform. Then the effect of pressing treatment for the starting GBCO particles on the microstructure and performance of sintered cathode was studied. The results demonstrated that, after being sintered under the same conditions, the cathode prepared from the treated GBCO particles showed a finer microstructure compared with that prepared from the raw GBCO particles. In addition, optimizing the morphology of the starting GBCO powder by pressing treatment could Unproved the cathode performance and made the polarization resistance of final cathode reduce from 1.33 Omega cm(2) to 0.40 Omega cm(2) at 600 degrees C. (C) 2011 Published by Elsevier Ltd and Techna Group S.r.l.