Synthesis of castor oil based plasticizers containing flame retarded group and their application in poly (vinyl chloride) as secondary plasticizer

被引：52
作者：
Jia, Pu-You [1 ]
Bo, Cai-Ying [1 ]
Zhang, Li-Qiang [1 ]
Hu, Li-Hong [1 ,2 ]
Zhang, Meng [1 ,2 ]
Zhou, Yong-Hong [1 ]
机构：
[1] CAF, Inst Chem Ind Forest Prod, Nanjing 210042, Jiangsu, Peoples R China
[2] CAF, Inst New Technol Forestry, Beijing 100091, Peoples R China
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2015年 / 28卷
关键词：
Castor oil; Epoxidized castor oil; Flame retardant; Plasticizer; Polyvinyl chloride; PVC; POLYESTER; MIGRATION; MECHANISM; PHOSPHATE;
D O I：
10.1016/j.jiec.2015.02.017
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Epoxidized castor oil (ECO) and castor oil phosphate ester (COPE) were synthesized. Structure of two functionalized castor oil was characterized with FTIR and H-1 NMR. Property of poly (vinyl chloride) PVC blends plasticized with ECO and (COPE) as secondary plasticizer was studied. The results indicated that thermal stability of plasticized PVC blends was improved, LOI value of PVC blends cooperated with COPE could reach 27.8%, flame retardant performance of COPE was put into effect by promoting polymer carbonization and forming a consolidated and thick flame retardant coating, which is effective to prohibit the heat flux and air incursion. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：217 / 224
页数：8
相关论文
共 30 条
  • [1] Bueno-Ferrer C, 2012, POLYM DEGRAD STABIL, V95, P2207, DOI DOI 10.1016/J.POLYMDEGRADSTAB.2010.01.027
  • [2] Chavan A. P., 2014, J IND ENG CHEM
  • [3] Migration of conventional and new plasticizers from PVC films into food simulants: A comparative study
    Coltro, Leda
    Pitta, Joyce Borghetti
    da Costa, Paulo Afonso
    Favaro Perez, Mary Angela
    de Araujo, Vanessa Aparecida
    Rodrigues, Rafaela
    [J]. FOOD CONTROL, 2014, 44 : 118 - 129
  • [4] Polyvinylchloride (PVC) and natural rubber films plasticized with a natural polymeric plasticizer obtained through polyesterification of rice fatty acid
    da Silva, Mariana Altenhofen
    Adeodato Vieira, Melissa Gurgel
    Gomes Macumoto, Andre Costa
    Beppu, Marisa Masumi
    [J]. POLYMER TESTING, 2011, 30 (05) : 478 - 484
  • [5] Epoxidation of modified natural plasticizer obtained from rice fatty acids and application on polyvinylchloride films
    Faria-Machado, Adelia Ferreira
    da Silva, Mariana Altenhofen
    Adeodato Vieira, Melissa Gurgel
    Beppu, Marisa Masumi
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 127 (05) : 3543 - 3549
  • [6] Analysis of phthalates in food products and packaging materials sold on the Belgian market
    Fierens, T.
    Servaes, K.
    Van Holderbeke, M.
    Geerts, L.
    De Henauw, S.
    Sioen, I.
    Vanermen, G.
    [J]. FOOD AND CHEMICAL TOXICOLOGY, 2012, 50 (07) : 2575 - 2583
  • [7] Genhai G., 2011, EUR POLYM J, V47, P1578
  • [8] Plasticizer for poly(vinyl chloride) from cardanol as a renewable resource material
    Greco, A.
    Brunetti, D.
    Renna, G.
    Mele, G.
    Maffezzoli, A.
    [J]. POLYMER DEGRADATION AND STABILITY, 2010, 95 (11) : 2169 - 2174
  • [9] Ioannis S., 2014, FOOD BIOPROCESS TECH, V7, P21
  • [10] Thermal stability of poly(vinyl chloride) with epoxidised soybean oil as primary plasticizer
    Karmalm, P.
    Hjertberg, T.
    Jansson, A.
    Dahl, R.
    [J]. POLYMER DEGRADATION AND STABILITY, 2009, 94 (12) : 2275 - 2281
123