Recent Advances in Transition Metal-Catalyzed Methylation Reactions

被引：133

作者：

Yan, Guobing ^{[1
]}

Borah, Arun Jyoti ^{[1
]}

Wang, Lianggui ^{[1
]}

Yang, Minghua ^{[1
]}

机构：

[1] Lishui Univ, Dept Chem, Lishui City 323000, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 07期

关键词：

cross-coupling; methylation; transition metal catalysts; C-H BONDS; CARBON-DIOXIDE; N-METHYLATION; COUPLING REACTIONS; VINYL HALIDES; ALPHA-METHYLATION; C(SP(3))-H BONDS; CARBOXYLIC-ACIDS; AROMATIC-AMINES; NITRO-COMPOUNDS;

D O I：

10.1002/adsc.201400984

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Methylation is one of the most fundamental synthetic transformations in organic chemistry, but usually employs hazardous and toxic reagents, such as methyl iodide, dimethyl sulfate, diazomethane and dimethyl carbonate. In order to address sustainable development and green strategies, synthetic chemists have devoted much effort to the discovery and development of new methylating reagents, which are successfully being applied in transition metal-catalyzed cross-coupling reactions. In this review, recent advances in this area are summarized, mainly including C-methylation, N-methylation and O-methylation. The respective reaction mechanisms are also discussed.

引用

页码：1333 / 1350

页数：18

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