A Facile and Efficient Synthesis of 3-Aryloxazolidin-2-ones from Isocyanates and Epoxides Promoted by MgI2 Etherate

被引：22

作者：

Zhang, Xingxian ^{[1
]}

Chen, Wei ^{[1
]}

Zhao, Chengfeng ^{[1
]}

Li, Cheng ^{[1
]}

Wu, Xiang ^{[1
]}

Chen, Wei Z. ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310032, Zhejiang, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2010年 / 40卷 / 24期

关键词：

Epoxide; isocyanate; MgI2; etherate; oxazolidinone; CATALYZED CYCLOADDITION; OXAZOLIDINONES; 2-OXAZOLIDONES; ALLYLATION; ALDEHYDES; OXIRANES;

D O I：

10.1080/00397910903470525

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We described a mild and efficient procedure for the synthesis of 3-aryloxazolidin-2-ones via the cycloaddition of isocyanates with epoxides in the presence of MgI2 etherate (MgI2 center dot(OEt2)n) in good yields.

引用

页码：3654 / 3659

页数：6

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