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A Facile and Efficient Synthesis of 3-Aryloxazolidin-2-ones from Isocyanates and Epoxides Promoted by MgI2 Etherate
被引:20
|作者:
Zhang, Xingxian
[1
]
Chen, Wei
[1
]
Zhao, Chengfeng
[1
]
Li, Cheng
[1
]
Wu, Xiang
[1
]
Chen, Wei Z.
[1
]
机构:
[1] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310032, Zhejiang, Peoples R China
关键词:
Epoxide;
isocyanate;
MgI2;
etherate;
oxazolidinone;
CATALYZED CYCLOADDITION;
OXAZOLIDINONES;
2-OXAZOLIDONES;
ALLYLATION;
ALDEHYDES;
OXIRANES;
D O I:
10.1080/00397910903470525
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
We described a mild and efficient procedure for the synthesis of 3-aryloxazolidin-2-ones via the cycloaddition of isocyanates with epoxides in the presence of MgI2 etherate (MgI2 center dot(OEt2)n) in good yields.
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页码:3654 / 3659
页数:6
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