Reversible surface functionalisation of emulsion-templated porous polymers using dithiophenol maleimide functional macromolecules

被引：14

作者：

Eissa, A. M. ^{[1
,2
,3
]}

Wilson, P. ^{[4
]}

Chen, C. ^{[1
]}

Collins, J. ^{[4
]}

Walker, M. ^{[5
]}

Haddleton, D. M. ^{[4
]}

Cameron, N. R. ^{[1
,2
]}

机构：

[1] Univ Warwick, Sch Engn, Coventry CV4 7AL, W Midlands, England

[2] Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia

[3] NRC, Chem Ind Res Div, Dept Polymers, El Bohoos St, Cairo 12311, Egypt

[4] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[5] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 70期

关键词：

THIOL-ENE CLICK; POLYHIPE SCAFFOLDS; POLYMERIZATION; CONJUGATION; CHEMISTRY; SUPPORTS;

D O I：

10.1039/c7cc03811a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new facile and efficient route for the chemical functionalisation of thiol-acrylate polyHIPE materials with responsive macromolecules using the highly emissive dithiomaleimide (DTM) linker is demonstrated. Functionalisation is found to be reversible upon addition of a thiol-containing compound, glutathione, resulting in switchable surface properties including fluorescence and wettability, hence broadening the scope of applications.

引用

页码：9789 / 9792

页数：4

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