Recent progress on phosphonate vinyl monomers and polymers therefore obtained by radical (co)polymerization

被引：45

作者：

David, G. ^{[1
]}

Negrell-Guirao, C. ^{[1
]}

Iftene, F. ^{[1
]}

Boutevin, B. ^{[1
]}

Chougrani, K. ^{[1
]}

机构：

[1] Ecole Natl Super Chim Montpellier, Inst Charles Gerhardt UMR CNRS 5253, Lab Ingn & Architecture Macromol, F-34296 Montpellier 05, France

来源：

POLYMER CHEMISTRY | 2012年 / 3卷 / 02期

关键词：

P-VINYLBENZYL PHOSPHONATE; ALPHA-AMINO PHOSPHONATES; METHYL-METHACRYLATE; ADHESIVE PROPERTIES; ACID SOLUTIONS; POLYMERIZATION; PHOTOPOLYMERIZATION; COPOLYMERIZATION; ETHER; ACRYLATE;

D O I：

10.1039/c1py00276g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This review paper gathers almost one hundred recent publications devoted to the synthesis and the free radical (co)polymerization of phosphonate vinyl monomers. Different synthetic approaches are discussed to introduce the phosphonate moieties into vinyl monomers, focusing especially on recent advances. Allyl-type, vinyl-type, styrenic-type and (meth)acrylic-type monomers bearing phosphonate groups (i.e. either mono or bisphosphonate) are considered with a special care about their reactivity in free radical (co)polymerization. It is shown that depending on the position of the phosphonate moieties the reactivity of the vinyl monomers is thus modified. For instance, free radical polymerization of vinyl phosphonate monomers is mainly dominated by transfer reactions, whereas the propagation rate of para-vinylbenzyl phosphonate monomers is enhanced by the phosphonate group. According to the structure of the phosphonate-bearing (co)polymers, the resulting properties are also investigated.

引用

页码：265 / 274

页数：10

共 79 条

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