Conductometric glucose biosensor made with cellulose and tin oxide hybrid nanocomposite

被引:74
作者
Mahadeva, Suresha K. [1 ]
Kim, Jaehwan [1 ]
机构
[1] Inha Univ, Dept Mech Engn, Ctr EAPap Actuator, Inchon 402751, South Korea
基金
新加坡国家研究基金会;
关键词
Glucose biosensor; Cellulose; Tin oxide; Liquid phase deposition; THIN-FILM; ELECTROCATALYTIC OXIDATION; CARBON NANOTUBES; GOLD ELECTRODES; IMMOBILIZATION; ENZYME; SENSOR; ADSORPTION; NANOWIRE; CHITOSAN;
D O I
10.1016/j.snb.2011.03.046
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper reports the feasibility study of glucose oxidase (GO(x)) immobilized cellulose-tin oxide (SnO2) hybrid nanocomposite as a glucose biosensor. Porous SnO2 layer was grown on regenerated cellulose films via liquid phase deposition technique with varying deposition time. Tin oxide was crystallized in the solution and formed nanocrystal coatings on the cellulose films. Enzyme (GO(x)) was immobilized into cellulose-SnO2 hybrid nanocomposite by physical absorption method. X-ray photoelectron spectroscopy analysis revealed the successful immobilization of GO(x) into the cellulose-SnO2 hybrid nanocomposite via covalent bonding between GO(x) and SnO2. The glucose biosensor under study is displayed linear response in the range of 0.5-12 mM with correlation coefficient of 0.96, which can cover the clinical region of glucose concentration. These results indicate that the cellulose-SnO2 hybrid nanocomposite can be an inexpensive, flexible and disposable glucose biosensor. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:177 / 182
页数:6
相关论文
共 30 条
[1]   Glucose sensor based on nano-baskets of tin oxide templated in porous alumina by plasma enhanced CVD [J].
Ansari, S. G. ;
Ansari, Z. A. ;
Wahab, Rizwan ;
Kim, Young-Soon ;
Khang, Gilson ;
Shin, Hyung-Shik .
BIOSENSORS & BIOELECTRONICS, 2008, 23 (12) :1838-1842
[2]   Electrocatalytic oxidation of sugars on silver-UPD single crystal gold electrodes in alkaline solutions [J].
Aoun, SB ;
Bang, GS ;
Koga, T ;
Nonaka, Y ;
Sotomura, T ;
Taniguchi, I .
ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (04) :317-320
[3]   PH-BASED ENZYME POTENTIOMETRIC SENSORS .2. GLUCOSE-SENSITIVE FIELD-EFFECT TRANSISTOR [J].
CARAS, SD ;
PETELENZ, D ;
JANATA, J .
ANALYTICAL CHEMISTRY, 1985, 57 (09) :1920-1923
[4]   Amperometric glucose biosensor based on sol-gel-derived metal oxide/Nafion composite films [J].
Choi, HN ;
Kim, MA ;
Lee, WY .
ANALYTICA CHIMICA ACTA, 2005, 537 (1-2) :179-187
[5]   ELECTRODE SYSTEMS FOR CONTINUOUS MONITORING IN CARDIOVASCULAR SURGERY [J].
CLARK, LC ;
LYONS, C .
ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1962, 102 (01) :29-&
[6]   Immobilisation of glucose oxidase within metallic nanotubes arrays for application to enzyme biosensors [J].
Delvaux, M ;
Demoustier-Champagne, S .
BIOSENSORS & BIOELECTRONICS, 2003, 18 (07) :943-951
[7]   Polypyrrole nanotube array sensor for enhanced adsorption of glucose oxidase in glucose biosensors [J].
Ekanayake, E. M. I. Mala ;
Preethichandra, D. M. G. ;
Kaneto, Keiichi .
BIOSENSORS & BIOELECTRONICS, 2007, 23 (01) :107-113
[8]   Transparent conducting oxides [J].
Ginley, DS ;
Bright, C .
MRS BULLETIN, 2000, 25 (08) :15-18
[9]   Nanotubular SnO2 templated by cellulose fibers:: Synthesis and gas sensing [J].
Huang, J ;
Matsunaga, N ;
Shimanoe, K ;
Yamazoe, N ;
Kunitake, T .
CHEMISTRY OF MATERIALS, 2005, 17 (13) :3513-3518
[10]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397