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Phase evolution and microwave dielectric properties of TiO2-modified (Mg0.95Co0.05)2TiO4 ceramics
被引:6
作者:
Huang, Cheng-Liang
[1
]
Chen, Jhih-Yong
[1
]
机构:
[1] Natl Cheng Kung Univ, Dept Elect Engn, Tainan 70101, Taiwan
关键词:
Crystal growth;
Dielectric response;
FREQUENCIES;
SYSTEM;
D O I:
10.1016/j.jallcom.2011.03.046
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Phase evolution and microwave dielectric properties of (1-x)(Mg0.95Co0.05)(2)TiO4-xTiO(2) (x = 0-1) ceramics prepared by the conventional mixed oxide route have been investigated. Increasing the TiO2 content would lead to a main phase transformation from (Mg0.95Co0.05)(2)TiO4 to (Mg0.95Co0.05)TiO3, (Mg0.95Co0.05)Ti2O5 and then TiO2. Not only did the TiO2 addition compensate the tau(f), it also lowered the sintering temperature of specimen. A huge drop of Q x f occurs at a 40-60 mol% TiO2 addition was attributed to the formation of (Mg0.95Co0.05)Ti2O5 phase. Specimen with x = 0.78 can possess an excellent combination of microwave dielectric properties: epsilon(r) similar to 24.77, Q x f similar to 38,500 GHz and tau(f)similar to-1.3 ppm/degrees C. (C) 2011 Published by Elsevier B.V.
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页码:6273 / 6275
页数:3
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