A Tetragonal 2D Array of Single-Molecule Magnets with Modulated Collective Behavior

被引：23
|
作者：
Burzuri, Enrique [2 ,3 ]
Campo, Javier [2 ,3 ]
Falvello, Larry R. [1 ,2 ]
Forcen-Vazquez, Elena [1 ,2 ]
Luis, Fernando [2 ,3 ]
Mayoral, Isabel [2 ,3 ]
Palacio, Fernando [2 ,3 ]
Saenz de Pipaon, Cristina [2 ,3 ]
Tomas, Milagros [1 ,2 ]
机构：
[1] Univ Zaragoza, CSIC, Dpto Quim Inorgan, E-50009 Zaragoza, Spain
[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
[3] Univ Zaragoza, CSIC, Dpto Fis Mat Condensada, E-50009 Zaragoza, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 10期
关键词：
cobalt; low-temperature physics; magnetic properties; single-molecule magnets; X-ray diffraction; HIGH-SPIN MOLECULES; CRYSTAL; CLUSTER; MAGNETIZATION; NANOMAGNETS; ANISOTROPY; NETWORKS; SQUARE; QUBITS; PHASE;
D O I：
10.1002/chem.201002980
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The counterion makes a difference: A square 2D array of cobalt citrate cubanes linked by bridging six-coordinate cobalt atoms (see graphic) displays collective magnetic behavior, which changes with subtle differences in the crystalline surroundings. The magnetic properties of two solid modifications, both synthesized by using wet chemistry techniques, reveal two different relaxation processes in each system at low temperatures, each with its own timescale.
引用
收藏
页码：2818 / 2822
页数：5
相关论文
共 50 条
  • [41] The Role of Radical Bridges in Polynuclear Single-Molecule Magnets
    Nguyen, Giang Truong
    Ungur, Liviu
    CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (30)
  • [42] A family of enneanuclear iron(II) single-molecule magnets
    Boudalis, Athanassios K.
    Sanakis, Yiannis
    Clemente-Juan, Juan Modesto
    Donnadieu, Bruno
    Nastopoulos, Vassilios
    Mari, Alain
    Coppel, Yanick
    Tuchagues, Jean-Pierre
    Perlepes, Spyros P.
    CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (08) : 2514 - 2526
  • [43] Approaching the uniaxiality of magnetic anisotropy in single-molecule magnets
    Wang, Chen
    Meng, Yin-Shan
    Jiang, Shang-Da
    Wang, Bing-Wu
    Gao, Song
    SCIENCE CHINA-CHEMISTRY, 2023, 66 (03) : 683 - 702
  • [44] Mononuclear Dysprosium Alkoxide and Aryloxide Single-Molecule Magnets
    Parmar, Vijay S.
    Mills, David P.
    Winpenny, Richard E. P.
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (28) : 7625 - 7645
  • [45] Heterospin Single-Molecule Magnets Based on Terbium Ions and TCNQF4 Radicals: Interplay between Single-Molecule Magnet and Phonon Bottleneck Phenomena Investigated by Dilution Studies
    Lopez, Nazario
    Prosvirin, Andrey V.
    Zhao, Hanhua
    Wernsdorfer, Wolfgang
    Dunbar, Kim R.
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (42) : 11390 - 11400
  • [46] Effect of nuclearity and symmetry on the single-molecule magnets behavior of seven-coordinated β-diketonate Dy(III) complexes
    Yao, Xu
    An, Guanghui
    Li, Yuxin
    Yan, Pengfei
    Li, Weizuo
    Li, Guangming
    JOURNAL OF SOLID STATE CHEMISTRY, 2019, 274 : 295 - 302
  • [47] 3d-4f Single Molecule-Magnets
    Zhang Xuhong
    Wang Shaping
    PROGRESS IN CHEMISTRY, 2010, 22 (09) : 1709 - 1719
  • [48] Giant Magnetoresistance in Carbon Nanotubes with Single-Molecule Magnets TbPc2
    Krainov, Igor V.
    Klier, Janina
    Dmitriev, Alexander P.
    Klyatskaya, Svetlana
    Ruben, Mario
    Wernsdorfer, Wolfgang
    Gornyi, Igor V.
    ACS NANO, 2017, 11 (07) : 6868 - 6880
  • [49] Single-molecule magnets beyond a single lanthanide ion: the art of coupling
    Chen, Yan-Cong
    Tong, Ming-Liang
    CHEMICAL SCIENCE, 2022, 13 (30) : 8716 - 8726
  • [50] Coordination Clusters of 3d-Metals That Behave as Single-Molecule Magnets (SMMs): Synthetic Routes and Strategies
    Maniaki, Diamantoula
    Pilichos, Evangelos
    Perlepes, Spyros P.
    FRONTIERS IN CHEMISTRY, 2018, 6
12345