Green synthesis of nanoporous Si/C anode using NaCl template with improved cycle life

被引:20
作者
Fan, Xu [1 ,2 ]
Jiang, Xiangping [1 ]
Wang, Wei [2 ]
Liu, Zhaoping [2 ]
机构
[1] Jingdezhen Ceram Inst, Dept Mat Sci & Engn, Jiangxi Key Lab Adv Ceram Mat, Jingdezhen 333001, Jiangxi, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn NIMTE, Ningbo 315201, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanocomposites; Porous materials; Silicon anodes; Green synthesis; Environment-friendly; ION BATTERY ANODES; HIGH-CAPACITY; SILICON; COMPOSITE; NANOPARTICLES; NANOSPHERES; ELECTRODES; FILM;
D O I
10.1016/j.matlet.2016.05.092
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Porous silicon/carbon (Si/C) structure has been proved of great help to enhance the electrochemical cycling performance of Si-based anode materials. Current fabrication of porous Si based anodes usually relies on the complicated chemical etching process with unavoidable pollution problem. Herein, a nanoporous Si/C composite was successfully fabricated by a facile spray drying and carbonization process. The environmentally benign NaCl is used as the sacrificing template for the generation of embedded nanopores, which can be easily removed by routine washing process. The as-prepared nanoporous Si/C anode exhibits a high reversible specific capacity of around 900 mAh g(-1) with 78.2% capacity retention after 100 cycles. This synthetic method paves a simple and environment-friendly way to build porous Si based anode with improved electrochemical performance which is significantly important for the industrial production. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:109 / 113
页数:5
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