(2,2′-Biquinoline-κ2N,N′)bis(nitrato-κ2O,O′)copper(II)

被引：3

作者：

Moreno, Yanko

Salgado, Yimmy

Garland, Maria Teresa

Baggio, Ricardo

机构：

[1] Univ Concepcion, Fac Ciencias Quim, Dept Quim Anal & Inorgan, Concepcion, Chile

[2] Univ Chile, Dept Fis, Fac Ciencias Fis & Matemat, Santiago, Chile

[3] Univ Chile, CIMAT, Santiago, Chile

[4] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S0108270107046513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title monomer, [Cu(NO3)(2)(C18H12N2)], the six-coordinated Cu-II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

引用

页码：M487 / M489

页数：3

共 16 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2] A new simplifying approach to molecular geometry description: the vectorial bond-valence model [J].

Angel Harvey, Miguel ;

Baggio, Sergio ;

Baggio, Ricardo .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2006, 62 (1038-1042) :1038-1042

[3]

[Anonymous], 1997, SHELXL 97 SHELXS 97

[4]

[Anonymous], 2000, SAINT NT

[5]

*BRUK AXS INC, 2001, SAINT NT

[6]

Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations

[7] Synthesis and optimization of experimental variables of a hybrid organic-inorganic compound [J].

Contreras, D. ;

Moreno, Y. ;

Salgado, Y. ;

Cardenas, G. ;

Baggio, R. ;

Pena, O. ;

Pivan, J. Y. .

NEW JOURNAL OF CHEMISTRY, 2007, 31 (10) :1751-1754

[8]

Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565

[9] New materials in hydrothermal synthesis [J].

Feng, SH ;

Xu, RR .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :239-247

[10] Synthesis and X-ray structures of two discrete metal complexes of 2,2′-bi-1.5-naphthyridine, a new ambivergent ligand [J].

Fitchett, Christopher M. ;

Steel, Peter J. .

POLYHEDRON, 2007, 26 (02) :400-405

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