Hf[N(SO2C8F17)2]4-catalyzed Friedel-Crafts acylation in a fluorous biphase system

被引：25
作者：
Hao, X [1 ]
Yoshida, A [1 ]
Nishikido, J [1 ]
机构：
[1] Noguchi Inst, Itabashi Ku, Tokyo 1730003, Japan
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 15期
关键词：
Lewis acid catalyst; fluorous biphase system; perfluorinated ligand; Friedel-Crafts acylation; regioselectivity;
D O I：
10.1016/j.tetlet.2005.02.065
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In a fluorous biphase system, Hf[N(SO2C8F17)(2)](4) complex (1 mol%) catalyzes Friedel-Crafts acylation of aromatic compounds such as anisole, toluene and chlorobenzene, and the corresponding aromatic ketones are obtained in satisfactory to high yields. The catalyst is selectively soluble in lower fluorous phase and can be easily recovered by simple phase separation. Furthermore, the catalyst can be reused without decrease of activity in most cases. (c) 2005 Elsevier Ltd. All rights reserved.
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收藏
页码：2697 / 2700
页数：4
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