Cyclodextrin-Catalyzed Organic Synthesis: Reactions, Mechanisms, and Applications

被引：74
作者：
Bai, Chang Cai [1 ]
Tian, Bing Ren [1 ]
Zhao, Tian [1 ]
Huang, Qing [1 ,2 ]
Wang, Zhi Zhong [1 ,2 ]
机构：
[1] Ningxia Med Univ, Sch Pharm, Yinchuan 750004, Peoples R China
[2] Minist Educ, Key Lab Hui Ethn Med Modernizat, Yinchuan 750004, Peoples R China
来源：
MOLECULES | 2017年 / 22卷 / 09期
关键词：
cyclodextrin; catalysis; mechanism; green chemistry; organic reaction; asymmetric reaction; NUCLEOPHILIC-SUBSTITUTION REACTIONS; ASYMMETRIC MICHAEL ADDITION; PHASE-TRANSFER CATALYST; 2016; NOBEL-PRIZE; BETA-CYCLODEXTRIN; INCLUSION COMPLEX; CONJUGATED ALKENES; ALDOL REACTION; WATER; OXIDATION;
D O I：
10.3390/molecules22091475
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Cyclodextrins are well-known macrocyclic oligosaccharides that consist of alpha-(1,4)linked glucose units and have been widely used as artificial enzymes, chiral separators, chemical sensors, and drug excipients, owing to their hydrophobic and chiral interiors. Due to their remarkable inclusion capabilities with small organic molecules, more recent interests focus on organic reactions catalyzed by cyclodextrins. This contribution outlines the current progress in cyclodextrin-catalyzed organic reactions. Particular emphases are given to the organic reaction mechanisms and their applications. In the end, the future directions of research in this field are proposed.
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页数：17
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