Amperometric hydrogen permeation measurement in iron using solid polymer electrolyte fuel cells

被引:5
|
作者
Ng, HC
Newman, RC
机构
[1] Univ Simon Bolivar, Dpto Ciencias Mat, Caracas 1080 A, Venezuela
[2] UMIST, Ctr Corros & Protect, Manchester M60 1QD, Lancs, England
关键词
iron; solid polymer electrolyte; hydrogen permeation; corrosion monitoring;
D O I
10.1016/j.corsci.2004.07.047
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrolytic hydrogen permeation through iron membranes was measured simultaneously by means of a solid polymer electrolyte fuel cell (SPEFC) and standard aqueous-phase hydrogen oxidation. Two configurations of SPEFC were tested: the first included a separate anode for hydrogen oxidation and the second used the iron membrane surface itself, plated with palladium, as the anode. The results showed a limiting hydrogen permeation flux for the first configuration but not for the second, which yielded about 64% of the correct output. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1197 / 1210
页数:14
相关论文
共 50 条
  • [31] Hydrogen storage and production by redox of iron oxide for polymer electrolyte fuel cell vehicles
    Otsuka, K
    Yamada, C
    Kaburagi, T
    Takenaka, S
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2003, 28 (03) : 335 - 342
  • [32] Sustainable Conversion of Glucose into Hydrogen Peroxide in a Solid Polymer Electrolyte Microbial Fuel Cell
    You, Shi-Jie
    Wang, Jing-Yuan
    Ren, Nan-Qi
    Wang, Xiu-Heng
    Zhang, Jin-Na
    CHEMSUSCHEM, 2010, 3 (03) : 334 - 338
  • [33] Performance of the hydrogen–air fuel cell with a Russian analogue of the Aquivion solid polymer electrolyte
    S. S. Ivanchev
    M. R. Tarasevich
    V. A. Bogdanovskaya
    O. V. Korchagin
    E. V. Burkovskii
    O. N. Primachenko
    V. S. Likhomanov
    Doklady Physical Chemistry, 2015, 464 : 227 - 230
  • [34] Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells
    Zhao, Dan
    Shui, Jiang-Lan
    Chen, Chen
    Chen, Xinqi
    Reprogle, Briana M.
    Wang, Dapeng
    Liu, Di-Jia
    CHEMICAL SCIENCE, 2012, 3 (11) : 3200 - 3205
  • [35] GAS PERMEATION PROPERTIES OF SOLID POLYMER ELECTROLYTE (SPE) MEMBRANES
    SAKAI, T
    TAKENAKA, H
    WAKABAYASHI, N
    KAWAMI, Y
    TORIKAI, E
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (06) : 1328 - 1332
  • [36] Polymer electrolyte membranes for fuel cells
    Zhang Hongwei
    Zhou Zhentao
    PROGRESS IN CHEMISTRY, 2008, 20 (04) : 602 - 619
  • [37] Membranes for polymer electrolyte fuel cells
    Glüsen, A
    Stolten, D
    CHEMIE INGENIEUR TECHNIK, 2003, 75 (11) : 1591 - 1597
  • [38] POLYMER ELECTROLYTE FUEL-CELLS
    GOTTESFELD, S
    ELECTROCHIMICA ACTA, 1995, 40 (03) : 283 - 283
  • [39] Polymer electrolyte membranes for fuel cells
    Lee, JS
    Quan, ND
    Hwang, JM
    Lee, SD
    Kim, H
    Lee, H
    Kim, HS
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2006, 12 (02) : 175 - 183
  • [40] Electrooxidation of hydrogen on nanostructured Pt/C catalysts for polymer electrolyte fuel cells
    Babic, B.
    Radmilovic, V.
    Krstajic, N.
    Kaludjerovic, B.
    RECENT DEVELOPMENTS IN ADVANCED MATERIALS AND PROCESSES, 2006, 518 : 283 - 288