Optical properties of annealed lead-tungstate single crystals

被引:0
作者
Kim, T [1 ]
机构
[1] Jeonju Natl Univ Educ, Dept Sci Educ, Jeonju 560757, South Korea
关键词
PbWO4; thermoluminescence; defects; annealing; optical absorption;
D O I
暂无
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
PbWO4 single crystals were grown in argon by using the Czochralski method and annealed in air. The thermoluminescence (TL) peaks below 110 K originate from intrinsic defect centers generated during growth, and those above 154 K are related to a local oxygen excess. The 420-nm absorption bands of annealed PbWO4 are related to the annealing temperature. The TL emission spectrum of as-grown PbWO4 mainly originate from the WO3 associated with oxygen vacancies or F-centers and that of annealed PbWO4 is due to the WO42- complex interacting with O2- owing to oxygen diffusion during the annealing process. The correlation between annealing and luminescence shows that structural defects are greatly influenced by the post-growth annealing.
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收藏
页码:1371 / 1374
页数:4
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