Liquid-phase catalytic hydroxylation of phenol using Cu(II), Ni(II) and Zn(II) complexes of amidate ligand encapsulated in zeolite-Y as catalysts

被引:31
作者
Maurya, MR [1 ]
Titinchi, SJJ
Chand, S
机构
[1] Indian Inst Technol, Dept Chem, Roorkee 247667, Uttar Pradesh, India
[2] Indian Inst Technol, Dept Chem Engn, Roorkee 247667, Uttar Pradesh, India
关键词
M-H(hybe)] complexes; zeolite-encapsulated metal complexes; hydroxylation of phenol; catechol and hydroquinone formation;
D O I
10.1023/A:1025706529969
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Copper(II), nickel(II) and zinc(II) complexes of amidate ligand 1,2-bis(2-hydroxybenzamido) ethane(H(2)hybe) encapsulated in the super cages of zeolite-Y have been prepared and characterized by spectroscopic studies and thermal as well as X-ray diffraction (XRD) patterns. These complexes catalyze the liquid-phase hydroxylation of phenol with H2O2 to catechol as a major product and hydroquinone as a minor product. Considering the concentration of substrate and oxidant, amount of catalyst, temperature of the reaction and volume of solvent, a best-suited reaction condition has been optimized to get maximum hydroxylation. Under the optimized reaction conditions, [Cu(hybe)]-Y has shown the highest conversion of 40% after 6 h, which is followed by [Ni(hybe)]-Y with 37% conversion and [Zn(hybe)]-Y has shown the poorest performance with 33% conversion. All these catalysts are more selective towards catechol formation (similar to90%), irrespective of their catalytic performance.
引用
收藏
页码:219 / 227
页数:9
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