A living free radical exchange reaction for the preparation of photoactive end-labeled monodisperse polymers

被引：51

作者：

Turro, NJ ^{[1
]}

Lem, G ^{[1
]}

Zavarine, IS ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

MACROMOLECULES | 2000年 / 33卷 / 26期

关键词：

D O I：

10.1021/ma001327n

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A 'living' free radical method is presented that is particularly useful when the comparison of a family of identical monodisperse polymers with different end groups is desired. In this approach, a single monodisperse polymer serves as the precursor for an exchange reaction that will substitute any desired nitroxide which is added to the system, in excess, at equilibrium conditions.

引用

页码：9782 / 9785

页数：4

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