Determination of novolac resin thermal decomposition products by pyrolysis gas chromatography mass spectrometry

被引:55
|
作者
Lytle, CA
Bertsch, W
McKinley, M
机构
[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
[2] Univ Alabama, Dept Engn, Tuscaloosa, AL 35487 USA
关键词
pyrolysis; gas chromatography mass spectrometry; novolac resin; thermal decomposition; metal casting;
D O I
10.1016/S0165-2370(98)00062-X
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) was used to identify the major volatile components produced by pyrolysis of a novolac resin. This resin is frequently used in the metal casting industry as a binder for sand molds. Quantitative analysis data of the pyrolysis products can serve as a model for the foundry industry to predict the amount of volatile organic compounds (VOCs) produced before actually carrying out the casting process. This allows the industry to comply with the Clean Air Act Amendments (CAAA) regarding the emissions of hazardous air pollutants (HAPs). (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:121 / 131
页数:11
相关论文
共 50 条
  • [31] Studies of the major degradation products of a higher alkyl polyacrylate using pyrolysis gas chromatography-mass spectrometry
    Li, JX
    Xu, HH
    Shi, J
    Li, CM
    Bao, CL
    ANALYTICA CHIMICA ACTA, 1999, 402 (1-2) : 311 - 318
  • [32] Comparative study of different algae pyrolysis using photoionization mass spectrometry and gas chromatography/mass spectrometry
    Niu, Qi
    Wang, Jinglan
    Cao, Congcong
    Cheng, Zhanjun
    Zhu, Yanan
    Wen, Wu
    Wang, Jian
    Pan, Yang
    Yan, Beibei
    Chen, Guanyi
    Ronsse, Frederik
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2021, 155 (155)
  • [33] Pyrolysis of foundry sand resins: A determination of organic products by mass spectrometry
    Dungan, RS
    Reeves, JB
    JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2005, 40 (08): : 1557 - 1567
  • [34] Determination of Acetochlor Residue in Food by Gas Chromatography and Gas Chromatography-Mass Spectrometry
    Dong Zhen-Lin
    Yang Chun-Guang
    Xiao Shan-Shan
    Zhao Jing-Hong
    Li Yi-Chen
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2009, 37 (05) : 698 - 702
  • [35] Gas chromatography mass spectrometry of 13 resin acids as their PFB esters
    Dethlefs, F
    Gerhardt, KO
    Stan, HJ
    JOURNAL OF MASS SPECTROMETRY, 1996, 31 (10): : 1163 - 1168
  • [36] Age determination of ballpoint pen ink by thermal desorption and gas chromatography-mass spectrometry
    Buegler, Juergen H.
    Buchner, Hans
    Dallmayer, Anton
    JOURNAL OF FORENSIC SCIENCES, 2008, 53 (04) : 982 - 988
  • [37] PYROLYSIS-GAS CHROMATOGRAPHY MASS-SPECTROMETRY OF A SERIES OF BILE-ACID SEQUESTRANTS
    HASKINS, NJ
    ECKERS, C
    MITCHELL, R
    ANALYST, 1992, 117 (09) : 1413 - 1416
  • [38] Pyrolysis gas chromatography mass spectrometry of two green phthalocyanine pigments and their identification in paint systems
    Germinario, Giulia
    van der Werf, Inez Dorothe
    Sabbatini, Luigia
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2015, 115 : 175 - 183
  • [39] DETERMINATION OF WET-STRENGTH RESIN IN PAPER BY PYROLYSIS-GAS CHROMATOGRAPHY
    YANO, T
    OHTANI, H
    TSUGE, S
    OBOKATA, T
    TAPPI JOURNAL, 1991, 74 (02): : 197 - 201
  • [40] Determination of 1,3-butadiene degradation products in air samples by thermal desorption-gas chromatography-mass spectrometry
    Vallecillos, Laura
    Sanmartin, Joel
    Maria Marce, Rosa
    Borrull, Francesc
    ATMOSPHERIC ENVIRONMENT, 2019, 196 : 95 - 102