Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal-organic frameworks (M = Ca, Sr and Ba)

被引：19
作者：
Ferrando-Soria, Jesus [1 ]
Rood, Marcus T. M. [1 ]
Julve, Miguel [1 ]
Lloret, Francesc [1 ]
Journaux, Yves [2 ]
Pasan, Jorge [3 ]
Ruiz-Perez, Catalina [3 ]
Fabelo, Oscar [4 ,5 ]
Pardo, Emilio [1 ]
机构：
[1] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol ICMOL, Valencia 46980, Spain
[2] Univ Paris 06, Inst Parisien Chim Mol, UMR 7201, F-75252 Paris, France
[3] Univ La Laguna, Dept Fis Fundamental 1, Lab Rayos & Mat Mol X, Tenerife 38201, Spain
[4] CSIC Univ Zaragoza, Inst Ciencia Mat Aragon, Zaragoza 50009, Spain
[5] Inst Laue Langevin, F-38042 Grenoble, France
来源：
CRYSTENGCOMM | 2012年 / 14卷 / 03期
关键词：
SINGLE-CHAIN MAGNETS; CRYSTAL-STRUCTURES; RATIONAL DESIGN; CO; COMPLEXES; CHEMISTRY; NI; FE; ANISOTROPY; SPIN;
D O I：
10.1039/c1ce06203d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The use of the mononuclear copper(II) complex, [Cu-II(Me(2)pma)(2)](2-) (Me(2)pma = N-2,6-dimethylphenyloxamate), as a bis(bidentate) metalloligand toward solvated alkaline earth metal cations affords a new series of oxamato-bridged heterobimetallic two-dimensional compounds with mixed square-octagonal [(Ca2Cu3II)-Cu-II] or square [(M2Cu3II)-Cu-II] (M = Sr and Ba) layered structures of (4.8(2)) and (4(4).6(2)) net topologies, respectively.
引用
收藏
页码：761 / 764
页数：4
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