Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal-organic frameworks (M = Ca, Sr and Ba)

被引：19

作者：

Ferrando-Soria, Jesus ^{[1
]}

Rood, Marcus T. M. ^{[1
]}

Julve, Miguel ^{[1
]}

Lloret, Francesc ^{[1
]}

Journaux, Yves ^{[2
]}

Pasan, Jorge ^{[3
]}

Ruiz-Perez, Catalina ^{[3
]}

Fabelo, Oscar ^{[4
,5
]}

Pardo, Emilio ^{[1
]}

机构：

[1] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol ICMOL, Valencia 46980, Spain

[2] Univ Paris 06, Inst Parisien Chim Mol, UMR 7201, F-75252 Paris, France

[3] Univ La Laguna, Dept Fis Fundamental 1, Lab Rayos & Mat Mol X, Tenerife 38201, Spain

[4] CSIC Univ Zaragoza, Inst Ciencia Mat Aragon, Zaragoza 50009, Spain

[5] Inst Laue Langevin, F-38042 Grenoble, France

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 03期

关键词：

SINGLE-CHAIN MAGNETS; CRYSTAL-STRUCTURES; RATIONAL DESIGN; CO; COMPLEXES; CHEMISTRY; NI; FE; ANISOTROPY; SPIN;

D O I：

10.1039/c1ce06203d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of the mononuclear copper(II) complex, [Cu-II(Me(2)pma)(2)](2-) (Me(2)pma = N-2,6-dimethylphenyloxamate), as a bis(bidentate) metalloligand toward solvated alkaline earth metal cations affords a new series of oxamato-bridged heterobimetallic two-dimensional compounds with mixed square-octagonal [(Ca2Cu3II)-Cu-II] or square [(M2Cu3II)-Cu-II] (M = Sr and Ba) layered structures of (4.8(2)) and (4(4).6(2)) net topologies, respectively.

引用

页码：761 / 764

页数：4

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