Viscose-Derived Activated Carbons Fibers as Highly Efficient Adsorbents for Dimethoate Removal from Water

被引:12
作者
Jocic, Ana [1 ]
Breitenbach, Stefan [2 ,3 ]
Bajuk-Bogdanovic, Danica [4 ]
Pasti, Igor A. [4 ]
Unterweger, Christoph [2 ]
Fuerst, Christian [2 ]
Lazarevic-Pasti, Tamara [1 ]
机构
[1] Univ Belgrade, Natl Inst Republ Serbia, VINCA Inst Nucl Sci, Mike Petrov Alasa 12-14, Belgrade 11000, Serbia
[2] Wood K Plus Kompetenzzentrum Holz GmbH, Altenberger Str 69, A-4040 Linz, Austria
[3] Johannes Kepler Univ Linz, Inst Chem Technol Inorgan Mat TIM, Altenberger Str 69, A-4040 Linz, Austria
[4] Univ Belgrade, Fac Phys Chem, Studentski Trg 12-16, Belgrade 11158, Serbia
关键词
water remediation; dimethoate removal; activated carbon fibers; ORGANOPHOSPHORUS PESTICIDES; AQUEOUS-SOLUTION; ADSORPTION; ENERGY; CHLORPYRIFOS; DEGRADATION;
D O I
10.3390/molecules27051477
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Extensive use of pesticides resulting in their accumulation in the environment presents a hazard for their non-target species, including humans. Hence, efficient remediation strategies are needed, and, in this sense, adsorption is seen as the most straightforward approach. We have studied activated carbon fibers (ACFs) derived from viscose fibers impregnated with diammonium hydrogen phosphate (DAHP). By changing the amount of DAHP in the impregnation step, the chemical composition and textural properties of ACFs are effectively tuned, affecting their performance for dimethoate removal from water. The prepared ACFs effectively reduced the toxicity of treated water samples, both deionized water solutions and spiked tap water samples, under batch conditions and in dynamic filtration experiments. Using the results of physicochemical characterization and dimethoate adsorption measurements, multiple linear regression models were made to reliably predict performance towards dimethoate removal from water. These models can be used to quickly screen among larger sets of possible adsorbents and guide the development of novel, highly efficient adsorbents for dimethoate removal from water.
引用
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页数:19
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