Sensitivity of the glass transition and melting in a metal-organic framework to ligand chemistry

被引：9

作者：

Madsen, Rasmus S. K. ^{[1
]}

Sarkar, Sounak ^{[2
]}

Iversen, Bo Brummerstedt ^{[2
]}

Yue, Yuanzheng ^{[1
]}

机构：

[1] Aalbrog Univ, Dept Chem & Biosci, DK-9220 Aalborg, Denmark

[2] Aarhus Univ, Dept Chem, DK-8000 Aarhus, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 06期

关键词：

LIQUID;

D O I：

10.1039/d1cc03541j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both T-m and T-g. The structural origin of this effect was explained.

引用

页码：823 / 826

页数：4

共 50 条

[31] Thermodynamic features and enthalpy relaxation in a metal-organic framework glass
Zhou, Chao
Stepniewska, Malwina
Longley, Louis
Ashling, Christopher W.
Chater, Philip A.
Keen, David A.
Bennett, Thomas D.
Yue, Yuanzheng
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (27) : 18291 - 18296
[32] A metal-organic framework with ultrahigh glass-forming ability
Qiao, Ang
Bennett, Thomas D.
Tao, Haizheng
Krajnc, Andraz
Mali, Gregor
Doherty, Cara M.
Thornton, Aaron W.
Mauro, John C.
Greaves, G. Neville
Yue, Yuanzheng
SCIENCE ADVANCES, 2018, 4 (03):
[33] Iodosylbenzene Coordination Chemistry Relevant to Metal-Organic Framework Catalysis
Cardenal, Ashley D.
Maity, Asim
Gao, Wen-Yang
Ashirov, Rahym
Hyun, Sung-Min
Powers, David C.
INORGANIC CHEMISTRY, 2019, 58 (16) : 10543 - 10553
[34] Metal-Organic Framework Capillary Microreactor for Application in Click Chemistry
Truter, Lara A.
Juan-Alcaniz, Jana
Kapteijn, Freek
Nijhuis, Tjeerd A.
Gascon, Jorge
Schouten, Jaap C.
CHEMCATCHEM, 2016, 8 (09) : 1692 - 1698
[35] Understanding the Chemistry of Metal Oxide to Metal-Organic Framework Reactions for Morphology Control
Freund, Ralph
Lanza, Arianna E.
Canossa, Stefano
Gemmi, Mauro
Goscianska, Joanna
Cauda, Valentina
Oschatz, Martin
Wuttke, Stefan
CHEMISTRY OF MATERIALS, 2023, 35 (05) : 1891 - 1900
[36] Reversible phase transition of metal-organic framework by de/rehydration
Sheu, Hwo-Shuenn
Shih, Wei-Ju
Lee, Gene-Hsiang
Yang, Ching-Chun
Wang, Chih-Chieh
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C719 - C719
[37] A new-AIE-ligand-based metal-organic framework "turn-on" sensor with extremely high sensitivity
Zhang, Jinfang
Li, Wenjing
Ren, Simeng
Zhao, Shunchang
Tao, Xingyu
Chen, Qinghan
Yin, Dejing
Zhang, Chi
NEW JOURNAL OF CHEMISTRY, 2023, 47 (35) : 16706 - 16712
[38] Metal-Organic Framework Glass Catalysts from Melting Glass-Forming Cobalt-Based Zeolitic Imidazolate Framework for Boosting Photoelectrochemical Water Oxidation
Song, Yurou
Ren, Yanhan
Cheng, Huijie
Jiao, Yuye
Shi, Shaobo
Gao, Lihua
Xie, Huimin
Gao, Junfeng
Sun, Licheng
Hou, Jungang
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (32)
[39] Crystal to Crystal Guest Exchange in a Mixed Ligand Metal-Organic Framework
Nelson, Andrew P.
Parrish, Damon A.
Cambrea, Lee R.
Baldwin, Lawrence C.
Trivedi, Nirupam J.
Mulfort, Karen L.
Farha, Omar K.
Hupp, Joseph T.
CRYSTAL GROWTH & DESIGN, 2009, 9 (11) : 4588 - 4591
[40] Unusual oxidation of an N-heterocycle ligand in a metal-organic framework
Han, Zhangang
Zhao, Yulong
Peng, Jun
Gomez-Garcia, Carlos J.
INORGANIC CHEMISTRY, 2007, 46 (14) : 5453 - 5455

← 1 2 3 4 5 →