(15-crown-5)caesium dicopper(I) triiodide, (15-crown-5)potassium dicopper(I) triiodide and (15-crown-5)rubidium dicopper(I) triiodide

被引：16
作者：
Nurtaeva, AK [1 ]
Holt, EM [1 ]
机构：
[1] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270197017502
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(15-Crown-5)caesium triiododicopper(I), [Cs(C10H20O5)][Cu2I3]. (15-crown-5)potassium triiododicopper(I), [K(C10H20O5)][CU2I3], and (15-crown-5)rubidium triiododicopper(I), [Rb(C10H20O5)][Cu2I3], are isostructural. They contain a polymeric Cu2I3- moiety, catena-poly[[copper(I)-mu(2)-iodo-copper(I)]-di-mu(3)-iodo], which may be viewed as a series of opposite edge-sharing Cu2I2 rhombs, with alternate units bridged by an additional I atom in an up, up, down, down pattern.
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页码：594 / 597
页数：4
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