Cooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks

被引：337

作者：

Sun, Lin-Bing ^{[1
]}

Li, Jian-Rong ^{[1
]}

Park, Jinhee ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 01期

基金：

美国国家科学基金会;

关键词：

HYDROGEN STORAGE; PORE-SIZE; DESIGN; SILICA; ENCAPSULATION; IMPROVEMENT; ROUTE; MICRO;

D O I：

10.1021/ja209698f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Despite great efforts, the development of a reliable way to assemble mesoporous metal-organic frameworks (mesoMOFs) remains a challenge. In this work, we have designed a cooperative template system, comprising a surfactant (cetyltrimethylammonium bromide) and a chelating agent (citric acid), for the generation of a mesoMOF containing a hierarchical system of mesopores interconnected with microspores. The surfactant molecules form micelles and the chelating agent bridges the MOF and the micelles, making self-assembly and crystal growth proceed under the direction of the cooperative template. However, when the surfactant or the chelating agent was applied individually, no mesoMOF was obtained.

引用

页码：126 / 129

页数：4

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