Cooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks

被引:336
作者
Sun, Lin-Bing [1 ]
Li, Jian-Rong [1 ]
Park, Jinhee [1 ]
Zhou, Hong-Cai [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
基金
美国国家科学基金会;
关键词
HYDROGEN STORAGE; PORE-SIZE; DESIGN; SILICA; ENCAPSULATION; IMPROVEMENT; ROUTE; MICRO;
D O I
10.1021/ja209698f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Despite great efforts, the development of a reliable way to assemble mesoporous metal-organic frameworks (mesoMOFs) remains a challenge. In this work, we have designed a cooperative template system, comprising a surfactant (cetyltrimethylammonium bromide) and a chelating agent (citric acid), for the generation of a mesoMOF containing a hierarchical system of mesopores interconnected with microspores. The surfactant molecules form micelles and the chelating agent bridges the MOF and the micelles, making self-assembly and crystal growth proceed under the direction of the cooperative template. However, when the surfactant or the chelating agent was applied individually, no mesoMOF was obtained.
引用
收藏
页码:126 / 129
页数:4
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