Pseudohalide assisted aerobic oxidation of alcohols in the presence of visible-light

被引：16
|
作者：
Shah, Sk. Sheriff [1 ]
Singh, N. D. Pradeep [1 ]
机构：
[1] Indian Inst Technol Kharagpur, Dept Chem, Kharagpur 721302, W Bengal, India
来源：
TETRAHEDRON LETTERS | 2018年 / 59卷 / 03期
关键词：
Pseudohalide; Visible light; Photocatalyst; Organic dyes; Benzyl alcohols; SELECTIVE PHOTOCATALYTIC OXIDATION; C-H BONDS; SOLVENT-FREE; METAL-FREE; PHOTOOXIDATION; PHOTOREDOX; CATALYSIS; TIO2; ALDEHYDES; THIOCYANATION;
D O I：
10.1016/j.tetlet.2017.12.018
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Pseudohalides are well known to do similar chemistry like halides. Thiocyanate, a pseudohalide acts like halides in many ways. Thiocyanate radicals (SCN) are generated from readily available thiocyanate salts using Rose Bengal through single electron transfer (SET) in the presence of visible light. Thiocyanate radicals abstract hydrogen like other halide radicals, so this aspect of chemistry was used for the oxidation of alcohols to their corresponding aldehydes using oxygen as the terminal oxidant. This method shows a broad scope and well tolerance towards various functional groups. (C) 2017 Published by Elsevier Ltd.
引用
收藏
页码：247 / 251
页数：5
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