Gas sensors based on doped-CNT/SnO2 composites for NO2 detection at room temperature

被引:85
作者
Leghrib, R. [1 ]
Felten, A. [2 ]
Pireaux, J. J. [2 ]
Llobet, E. [1 ]
机构
[1] Univ Rovira & Virgili, MINOS, EMaS, Tarragona 43007, Spain
[2] Univ Namur, LISE, B-5000 Namur, Belgium
关键词
Gas sensors; N- or B-doped carbon nanotubes; Metal oxides; NO2; detection; WALLED CARBON NANOTUBES; TIN OXIDE; ELECTRICAL-PROPERTIES; SENSING PROPERTIES; HYBRID MATERIALS; FILMS; SENSITIVITY; VAPOR;
D O I
10.1016/j.tsf.2011.04.186
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
For the first time nitrogen or boron doped carbon nanotubes were added into a SnO2 matrix to develop a new hybrid CNTs/SnO2 gas sensors. The hybrid sensor is utilised to detect low ppb concentrations of NO2 in air, by measuring resistance changes of thin CNTs/SnO2 films. The tests are performed at room temperature. For comparison, pure SnO2 and N or B-substituted CNT sensors are also examined. Comparative gas sensing results reveal that the CNTs/SnO2 hybrid sensors exhibit much higher response towards NO2, at least by a factor of 10, and good baseline recovery properties at room temperature than the blank SnO2 and the N or B-substituted CNT sensors. This finding shows that doping SnO2 with low quantity of CNTs doped with heteroatoms can dramatically improve sensitivity. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:966 / 970
页数:5
相关论文
共 40 条
[1]   Light enhanced NO2 gas sensing with tin oxide at room temperature:: conductance and work function measurements [J].
Anothainart, K ;
Burgmair, A ;
Karthigeyan, A ;
Zimmer, M ;
Eisele, I .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :580-584
[2]   Computational study of B- or N-doped single-walled carbon nanotubes as NH3 and NO2 sensors [J].
Bai, Lu ;
Zhou, Zhen .
CARBON, 2007, 45 (10) :2105-2110
[3]   ELECTRICAL-PROPERTIES AND IMPROVEMENT OF THE GAS SENSITIVITY IN MULTIPLE-DOPED SNO2 [J].
BEHR, G ;
FLIEGEL, W .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 26 (1-3) :33-37
[4]   Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization [J].
Chen, RJ ;
Zhang, YG ;
Wang, DW ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) :3838-3839
[5]   The enhanced ethanol sensing properties of multi-walled carbon nanotubes/SnO2 core/shell nanostructures [J].
Chen, Yujin ;
Zhu, Chunling ;
Wang, Taihong .
NANOTECHNOLOGY, 2006, 17 (12) :3012-3017
[6]   Low power micro-gas sensors using mixed SnO2 nanoparticles and MWCNTs to detect NO2, NH3, and xylene gases for ubiquitous sensor network applications [J].
Choi, Kwang-Yong ;
Park, Joon-Shik ;
Park, Kwang-Bum ;
Kim, Hyun Jae ;
Park, Hyo-Derk ;
Kim, Seong-Dong .
SENSORS AND ACTUATORS B-CHEMICAL, 2010, 150 (01) :65-72
[7]   Response speed of SnO2-based H2S gas sensors with CuO nanoparticles [J].
Chowdhuri, A ;
Gupta, V ;
Sreenivas, K ;
Kumar, R ;
Mozumdar, S ;
Patanjali, PK .
APPLIED PHYSICS LETTERS, 2004, 84 (07) :1180-1182
[8]   Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts [J].
Comini, E ;
Faglia, G ;
Sberveglieri, G ;
Pan, ZW ;
Wang, ZL .
APPLIED PHYSICS LETTERS, 2002, 81 (10) :1869-1871
[9]   UV light activation of tin oxide thin films for NO2 sensing at low temperatures [J].
Comini, E ;
Faglia, G ;
Sberveglieri, G .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 78 (1-3) :73-77
[10]   Boron-doping effects in carbon nanotubes [J].
Hsu, WK ;
Firth, S ;
Redlich, P ;
Terrones, M ;
Terrones, H ;
Zhu, YQ ;
Grobert, N ;
Schilder, A ;
Clark, RJH ;
Kroto, HW ;
Walton, DRM .
JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (06) :1425-1429