A novel magnetically separable TiO2/CoFe2O4 nanofiber with high photocatalytic activity under UV-vis light

被引:109
作者
Li, Cong-Ju [1 ]
Wang, Jiao-Na [1 ]
Wang, Bin [1 ]
Gong, Jian Ru [2 ]
Lin, Zhang [3 ]
机构
[1] Beijing Inst Fash Technol, Beijing Key Lab Clothing Mat R&D & Assessment, Beijing 100029, Peoples R China
[2] Natl Ctr Nanosci & Technol China, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
基金
北京市自然科学基金;
关键词
Composites; Nanostructures; Sol-gel chemistry; X-ray diffraction; Catalytic properties; FE-DOPED TIO2; POLYMER NANOFIBERS; NANOPARTICLES; DEGRADATION; FABRICATION; COMPOSITE; FIBERS;
D O I
10.1016/j.materresbull.2011.11.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel magnetically separable heterogeneous photocatalyst TiO2/CoFe2O4 nanofiber was prepared by sot-gel method and electrospinning technology, followed by heat treatment at 550 degrees C for 2 h. The phase structure, morphology and magnetic property of the composite nanofibers were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscope and vibrating sample magnetometer analysis. The photocatalytic studies of TiO2/CoFe2O4 fibers suggested that the presence of CoFe2O4 not only enhanced the absorbance of UV light, but also broadened the response region to visible light. The decolorizing efficiency of methylene blue (MB) solution reaches 95.87% over TiO2/CoFe2O4 nanofibers under 300 W Hg lamp after 5 h, which is close to that of Degussa P25. Furthermore, these fibers can be collected with a magnet for reuse and effectively avoid the secondary pollution of the treated water. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:333 / 337
页数:5
相关论文
共 27 条
[1]   Photocatalytic activity of titania fibers obtained by electrospinning [J].
Alves, A. K. ;
Berutti, F. A. ;
Clemens, F. J. ;
Graule, T. ;
Bergmann, C. P. .
MATERIALS RESEARCH BULLETIN, 2009, 44 (02) :312-317
[2]   Synthesis of a magnetically separable composite photocatalyst with high photocatalytic activity under sunlight [J].
Ao, Yanhui ;
Xu, Jingjing ;
Zhang, Songhe ;
Fu, Degang .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2009, 70 (06) :1042-1047
[3]   Magnetically separable titania-coated nickel ferrite photocatalyst [J].
Chung, YS ;
Park, SB ;
Kang, DW .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 86 (2-3) :375-381
[4]  
Cong-ju L, 2011, MAT RES B, V46, P119
[5]   Polymer nanofibers assembled by electrospinning [J].
Frenot, A ;
Chronakis, IS .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2003, 8 (01) :64-75
[6]   A review on polymer nanofibers by electrospinning and their applications in nanocomposites [J].
Huang, ZM ;
Zhang, YZ ;
Kotaki, M ;
Ramakrishna, S .
COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (15) :2223-2253
[7]   Fabrication and characterization of cobalt ferrite (CoFe2O4) nanofibers by electrospinning [J].
Ju, Young-Wan ;
Park, Jae-Hyun ;
Jung, Hong-Ryun ;
Cho, Sung-June ;
Lee, Wan-Jin .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2008, 147 (01) :7-12
[8]   Functionalization of Electrospun Titanium Oxide Nanofibers with Silver Nanoparticles: Strongly Effective Photocatalyst [J].
Kanjwal, Muzafar A. ;
Barakat, Nasser A. M. ;
Sheikh, Faheem A. ;
Khil, Myung Seob ;
Kim, Hak Yong .
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2010, 7 :E54-E63
[9]   Fabrication and Characterization of TiO2/Poly(dimethyl siloxane) Composite Fibers with Thermal and Mechanical Stability [J].
Kim, Young Bum ;
Cho, Donghwan ;
Park, Won Ho .
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (01) :449-454
[10]   Highly Reactive Multilayer-Assembled TiO2 Coating on Electrospun Polymer Nanofibers [J].
Lee, Jung Ah ;
Krogman, Kevin C. ;
Ma, Minglin ;
Hill, Randal M. ;
Hammond, Paula T. ;
Rutledge, Gregory C. .
ADVANCED MATERIALS, 2009, 21 (12) :1252-+