Application of a Schottky barrier to dye-sensitized solar cells (DSSCs) with multilayer thin films of photoelectrodes

被引:8
作者
Chang, Ho [1 ]
Cho, Kun-Ching [2 ]
Kuo, Chin-Guo [3 ]
Kao, Mu-Jung [4 ]
Huang, Kuohsiu-David [4 ]
Chu, Kung-Hui [2 ]
Lin, Xiu-Ping [1 ]
机构
[1] Natl Taipei Univ Technol, Dept Mech Engn, Taipei 10608, Taiwan
[2] Texas A&M Univ, Dept Civil Engn, College Stn, TX 77843 USA
[3] Natl Taiwan Normal Univ, Dept Mechatron Technol, Taipei 10610, Taiwan
[4] Natl Taipei Univ Technol, Dept Vehicle Engn, Taipei 10608, Taiwan
关键词
Dye-sensitized solar cells (DSSCs); Schottky barrier; Au nanoparties; TiO2 nanotubes (Tnt); TITANIA NANOTUBES; PLASMON RESONANCE; TIO2; ELECTRODE; NANOPARTICLES; IMPROVEMENT; CONVERSION;
D O I
10.1016/j.jallcom.2011.01.162
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study combines Au nanoparticles with TiO2 nanoparticles to form a Schottky barrier, and applies it to the photoelectrode thin film of dye-sensitized solar cells (DSSCs). First, commercial TiO2 powder (Degussa P25) is put in the alkaline solution to prepare for TiO nanotubes (Tnt) by using hydrothermal treatment. Tnt are sintered at 550 degrees C to obtain Tnt-C550 particles. In addition, TiO2 nanoparticles (H180) prepared by subjecting Tnt to two cycles of hydrothermal treatment. H180 served as the first layer, and Tnt-C550 as the second. The third layer adopts salt reduction method to prepare for Au nanoparticles. Experimental results show that the DSSCs prepared with three layers of photoelectrode thin films (H180/Tnt-C550/Au) enhanced the light-to-electricity efficiency of DSSCs by as high as 21% (6.34-7.65%). (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:S486 / S489
页数:4
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