Hydroformylation of 1-hexene with rhodium in non-aqueous ionic liquids: how to design the solvent and the ligand to the reaction

被引：155

作者：

Favre, F ^{[1
]}

Olivier-Bourbigou, H ^{[1
]}

Commereuc, D ^{[1
]}

Saussine, L ^{[1
]}

机构：

[1] IFP Energies Nouvelles, F-92852 Rueil Malmaison, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 15期

关键词：

D O I：

10.1039/b104155j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A wide range of ionic liquids based on imidazolium and pyrrolidinium cations and weakly coordinating anions proved to be efficient solvents for the biphasic rhodium catalyzed hydroformylation of 1-hexene; the reaction rate and regioselectivity, and the retention of the rhodium can be optimized by fitting the nature of the anions and cations of the ionic liquid and the modified phosphite or phosphine ligands.

引用

页码：1360 / 1361

页数：2

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