Manganese porphyrin immobilized on magnetic MCM-41 nanoparticles as an efficient and reusable catalyst for alkene oxidations with sodium periodate

被引：48

作者：

Hajian, Robabeh ^{[1
]}

Ehsanikhah, Amin ^{[1
]}

机构：

[1] Yazd Univ, Dept Chem, Yazd 89195741, Iran

来源：

CHEMICAL PHYSICS LETTERS | 2018年 / 691卷

关键词：

MCM-41; Catalytic epoxidation; Heterogeneous catalyst; Fe3O4; Manganese porphyrin; Nanostructures; RECOVERABLE NANOCATALYST; HYDROCARBON OXIDATION; EPOXIDATION; SILICA; METALLOPORPHYRINS; COMPLEXES; NAIO4; ACID;

D O I：

10.1016/j.cplett.2017.11.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study describes the immobilization of tetraphenylporphyrinatomanganese(III) chloride, (MnPor), onto imidazole functionalized MCM-41 with magnetite nanoparticle core (Fe3O4@MCM-41-Im). The resultant material (Fe3O4@MCM-41-Im@MnPor) was characterized by X-ray diffractometry (XRD), Fourier transform infra-red (FT-IR), diffuse reflectance UV-Vis spectrophotometry (DR UV-Vis), field emission scanning electron microscopy (FESEM), Inductively coupled plasma (ICP), analyzer transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) surface area. This new heterogenized catalyst was applied as an efficient catalyst for the epoxidation of a variety of cyclic and linear olefins with NaIO4 under mild conditions. The prepared catalyst can be easily recovered through the application of an external magnet, and reused several times without any significant decrease in activity and magnetic properties. (C) 2017 Elsevier B.V. All rights reserved.

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页码：146 / 154

页数：9

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