Real-time monitoring of hemicellulose liquefaction in ethylene glycol

被引:2
作者
Wang, C. [1 ,2 ,3 ]
Zhang, H. R. [1 ,2 ,3 ]
Guo, H. J. [1 ,2 ,3 ]
Shi, S. L. [1 ,2 ,3 ]
Xiong, L. [1 ,2 ,3 ]
Chen, X. D. [1 ,2 ,3 ]
机构
[1] Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou, Guangdong, Peoples R China
[2] Chinese Acad Sci, Key Lab New & Renewable Energy Res & Dev, Guangzhou Inst Energy Convers, Guangzhou, Guangdong, Peoples R China
[3] Chinese Acad Sci, R&D Ctr Xuyi Attapulgite Appl Technol, Guangzhou Inst Energy Convers, Xuyi, Peoples R China
基金
中国国家自然科学基金;
关键词
Ethylene glycol; GC-MS; liquefaction; online monitoring; xylan; XYLANS; LIGNIN;
D O I
10.1080/15567036.2015.1062825
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Xylan was used as a model material to study the liquefaction of hemicellulose in the presence of ethylene glycol. The ReactIR(TM) reaction analysis system was used to monitor the entire liquefaction process online. The results showed that xylan was decomposed and transferred to liquid phase. The gel permeation chromatography results of the liquid products showed that the weight average molecular of xylan decreased significantly to around 1728 g/mol after liquefaction. Gas chromatography-mass spectrometry revealed that the ethylene glycol liquefaction products from xylan include ethylene glycol and its derivatives, alcohols, aldehydes, ketones, some acids and their esters.
引用
收藏
页码:2517 / 2523
页数:7
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