Polymers Containing Nickel(II) Complexes of Goedken's Macrocycle: Optimized Synthesis and Electrochemical Characterization

被引：10

作者：

Paquette, Joseph A. ^{[1
,2
]}

Sauve, Ethan R. ^{[1
,2
]}

Gilroy, Joe B. ^{[1
,2
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Western Ontario, Ctr Adv Mat & Biomat Res CAMBR, London, ON N6A 5B7, Canada

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2015年 / 36卷 / 07期

基金：

加拿大自然科学与工程研究理事会;

关键词：

electrochemistry; macrocycles; metallopolymers; nickel(II); redox chemistry; METAL-CONTAINING POLYMERS; BLOCK-COPOLYMERS; OXIDATIVE ELECTROPOLYMERIZATION; REDOX; METALLOPOLYMERS; POLYMERIZATION; SURFACE; TRANSITION; ELECTRODES; LIGANDS;

D O I：

10.1002/marc.201400500

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis and characterization of a new class of nickel-containing polymers is described. The optimized copolymerization of alkyne-bearing nickel(II) complexes of Goedken's macrocycle (4,11-dihydro-5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine) and brominated 9,9-dihexylfluorene produced polymers with potential application as functional redox-active materials. The title polymers exhibit electrochemically reversible, ligand-centered oxidation events at 0.24 and 0.73 V versus the ferrocene/ferrocenium redox couple. They also display exceptional thermal stability and interesting absorption properties due to the presence of the macrocyclic nickel(II) complexes and -conjugated units incorporated in their backbones.

引用

页码：621 / 626

页数：6

共 53 条

[41]

2-0

[42] Syntheses, crystal structure and electrochemical characterization of ferrocene-containing nickel(II) complexes with 4,11-dihydro-5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine [J].

Shen, Xuan ;

Miyashita, Hironori ;

Qi, Li ;

Zhu, Dun-Ru ;

Hashimoto, Mamoru ;

Sakata, Kazunori .

POLYHEDRON, 2008, 27 (14) :3105-3111

[43] Photonics of a Conjugated Organometallic Pt-Ir Polymer and Its Model Compounds Exhibiting Hybrid CT Excited States [J].

Soliman, Ahmed M. ;

Fortin, Daniel ;

Zysman-Colman, Eli ;

Harvey, Pierre D. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2012, 33 (6-7) :522-527

[44] Patchy Nanocapsules of Poly(vinylferrocene)-Based Block Copolymers for Redox-Responsive Release [J].

Staff, Roland H. ;

Gallei, Markus ;

Mazurowski, Markus ;

Rehahn, Matthias ;

Berger, Ruediger ;

Landfester, Katharina ;

Crespy, Daniel .

ACS NANO, 2012, 6 (10) :9042-9049

[45] Migration Insertion Polymerization (MIP) of Cyclopentadienyldicarbonyldiphenylphosphinopropyliron (FpP): A New Concept for Main Chain Metal-Containing Polymers (MCPs) [J].

Wang, Xiaosong ;

Cao, Kai ;

Liu, Yibo ;

Tsang, Brian ;

Liew, Sean .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (09) :3399-3402

[46] Functional soft materials from metallopolymers and metallosupramolecular polymers [J].

Whittell, George R. ;

Hager, Martin D. ;

Schubert, Ulrich S. ;

Manners, Ian .

NATURE MATERIALS, 2011, 10 (03) :176-188

[47] Formation of dynamic metallo-copolymers by inkjet printing: towards white-emitting materials [J].

Wild, Andreas ;

Teichler, Anke ;

Ho, Cheuk-Lam ;

Wang, Xing-Zhu ;

Zhan, Hongmei ;

Schluetter, Florian ;

Winter, Andreas ;

Hager, Martin D. ;

Wong, Wai-Yeung ;

Schubert, Ulrich S. .

JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (09) :1812-1822

[48] A comparison of the effects of symmetry and magnetoanisotropy on paramagnetic relaxation in related dysprosium single ion magnets [J].

Williams, Ursula J. ;

Mahoney, Brian D. ;

DeGregorio, Patrick T. ;

Carroll, Patrick J. ;

Nakamaru-Ogiso, Eiko ;

Kikkawa, James M. ;

Schelter, Eric J. .

CHEMICAL COMMUNICATIONS, 2012, 48 (45) :5593-5595

[49] Metallated conjugated polymers as a new avenue towards high-efficiency polymer solar cells [J].

Wong, Wai-Yeung ;

Wang, Xing-Zhu ;

He, Ze ;

Djurisic, Aleksandra B. ;

Yip, Cho-Tung ;

Cheung, Kai-Yin ;

Wang, Hai ;

Mak, Chris S. K. ;

Chan, Wai-Kin .

NATURE MATERIALS, 2007, 6 (07) :521-527

[50] Recent Progress on the Photonic Properties of Conjugated Organometallic Polymers Built Upon the trans-Bis(para-ethynylbenzene)bis(phosphine)platinum(II) Chromophore and Related Derivatives [J].

Wong, Wai-Yeung ;

Harvey, Pierre D. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (08) :671-713

← 1 2 3 4 5 6 →