A Phosphorus/Aluminum-Based Frustrated Lewis Pair as an Ion Pair Receptor: Alkali Metal Hydride Adducts and Phase-Transfer Catalysis

被引：94

作者：

Appelt, Christian ^{[2
]}

Slootweg, J. Chris ^{[1
]}

Lammertsma, Koop ^{[1
]}

Uhl, Werner ^{[2
]}

机构：

[1] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands

[2] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 24期

关键词：

alkali metals; density functional calculations; frustrated Lewis pairs; hydrides; silanes; COMPLEX REDUCING AGENTS; REDUCTION REACTIONS; CRYSTAL-STRUCTURES; LITHIUM HYDRIDE; COORDINATION; ACTIVATION; HYDROGENATION; DERIVATIVES; REAGENTS; LIGANDS;

D O I：

10.1002/anie.201201855

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Helpful frustration: The geminal phosphorus/aluminum-based frustrated Lewis pair (Mes 2P)(tBu 2Al)C-C(H)Ph (Mes=2,4,6-Me 3C 6H 2) forms stable adducts with alkali metal hydrides (LiH, NaH, KH). These molecular hydride complexes display enhanced reactivity, which was demonstrated by the catalytic transformation of chlorotriphenylsilane to the corresponding hydride through a frontside S N2-f@Si pathway. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5911 / 5914

页数：4

共 2 条

[1] Dehydrochlorination of Carboxylic Acid Chlorides by an Aluminum/Phosphorus-Based Frustrated Lewis Pair and the Formation of Ketene Adducts
Uhl, Werner
Wegener, Philipp
Wuerthwein, Ernst-Ulrich
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (12-13): : 2102 - 2108
[2] Reaction of an Al/P-based frustrated Lewis pair with benzophenone: formation of adducts and aluminium alcoholates via β-hydride elimination
Uhl, Werner
Wegener, Philipp
Layh, Marcus
Hepp, Alexander
Wuerthwein, Ernst-Ulrich
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2016, 71 (10): : 1043 - 1050

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